Home
Class 12
CHEMISTRY
Assertion : N(CH(2)CH(2)NH(2))(3) and ED...

Assertion : `N(CH_(2)CH_(2)NH_(2))_(3)` and EDTA are examples of polydentate ligands .
Reason : Ligands which can ligate through two different atoms is called polydentate ligand .

A

If both Assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false

D

if both assertion and reason are false

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understanding the Assertion The assertion states that `N(CH₂CH₂NH₂)₃` and EDTA are examples of polydentate ligands. - **Polydentate Ligands**: These are ligands that can attach to a central metal atom through multiple donor atoms. - **N(CH₂CH₂NH₂)₃**: This ligand has three amine (NH₂) groups, which can donate lone pairs of electrons to a metal center, making it a polydentate ligand. - **EDTA**: Ethylenediaminetetraacetic acid (EDTA) has multiple donor atoms (two nitrogen and four oxygen atoms) that can coordinate with a metal ion, thus it is also a polydentate ligand. ### Conclusion for Step 1 Both `N(CH₂CH₂NH₂)₃` and EDTA are indeed polydentate ligands. Therefore, the assertion is **correct**. ### Step 2: Understanding the Reason The reason states that ligands which can ligate through two different atoms are called polydentate ligands. - **Ambidentate Ligands**: Ligands that can coordinate to a metal through two different atoms (but not necessarily at the same time) are known as ambidentate ligands. - This definition does not accurately describe polydentate ligands, which are defined by having multiple donor atoms that can bind simultaneously. ### Conclusion for Step 2 The reason provided is **incorrect** because it misdefines polydentate ligands. ### Final Conclusion - The assertion is correct: `N(CH₂CH₂NH₂)₃` and EDTA are polydentate ligands. - The reason is incorrect: the definition given is for ambidentate ligands, not polydentate ligands. ### Answer Thus, the final answer is that the assertion is correct, and the reason is incorrect.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understanding the Assertion The assertion states that `N(CH₂CH₂NH₂)₃` and EDTA are examples of polydentate ligands. - **Polydentate Ligands**: These are ligands that can attach to a central metal atom through multiple donor atoms. - **N(CH₂CH₂NH₂)₃**: This ligand has three amine (NH₂) groups, which can donate lone pairs of electrons to a metal center, making it a polydentate ligand. - **EDTA**: Ethylenediaminetetraacetic acid (EDTA) has multiple donor atoms (two nitrogen and four oxygen atoms) that can coordinate with a metal ion, thus it is also a polydentate ligand. ...
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    NCERT FINGERTIPS ENGLISH|Exercise Warners Theory Of Coordination Compound|13 Videos
  • COORDINATION COMPOUNDS

    NCERT FINGERTIPS ENGLISH|Exercise Definition Of Some Important Terms Pertaining To Coordination Compounds|13 Videos
  • COORDINATION COMPOUNDS

    NCERT FINGERTIPS ENGLISH|Exercise NCERT EXEMPLAR PROBLEMS|14 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    NCERT FINGERTIPS ENGLISH|Exercise NCERT Exemplar|15 Videos
  • ELECTROCHEMISTRY

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos

Similar Questions

Explore conceptually related problems

CH_(3)CH_(2)NH_(2) is soluble in :-

Assertion : CH_2=CH-CH_2-X is an examples of allyl halides. Reason: These are the compounds in which the halogen atom is called to an sp^2 hybridised carbon atom.

Write IUPAC name of CH_(3)-CH_(2)-NH_(2)

Assertion Glycinate ion is an example of monodentate ligand Reason It contains N as the only donor atom .

Find the number of ligand (s) which is//are polydentate ligand en, dmg dien EDTA .

Assertion: Hydrazine is a neutral ligand. Reason: It has two N as donor atoms and behaves as a chelating ligand.

Assertion (A) Linkage isomerism arises in coordination compounds containing ambidnetate ligand. Reason (R) Ambidentate ligand has two different donor atoms.

Assertion (A) Linkage isomerism arises in coordination compounds containing ambidnetate ligand. Reason (R) Ambidentate ligand has two different donor atoms.

Assertion : In CH_(2)=C=CH_(2) , all the carbon atoms are sp^(2) -hybridized. Reason : All the hydrogen atoms lie in one plane.

Out of CH_(3)-NH_(2) and (CH_(3))_(3)N which one has higher boiling point?