Home
Class 12
CHEMISTRY
Assertion : In tetrahedral complexes lo...

Assertion : In tetrahedral complexes low spin configuration are rarely observed .
Reason : `Delta_(t) = ((4)/(9)) Delta_(0)`

A

If both Assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false

D

if both assertion and reason are false

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason related to tetrahedral complexes, we will analyze both statements step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that "In tetrahedral complexes, low spin configurations are rarely observed." - Tetrahedral complexes are typically formed by transition metals with a coordination number of 4, leading to sp³ hybridization. 2. **Hybridization in Tetrahedral Complexes**: - In tetrahedral complexes, the hybridization is sp³, meaning that the orbitals involved are one s orbital and three p orbitals. - Importantly, the 3d orbitals are not utilized in the hybridization process for tetrahedral complexes. 3. **Spin States**: - Low spin configurations occur when there is a strong field ligand that causes a significant splitting of the d-orbitals, allowing electrons to pair up in the lower energy orbitals before occupying higher energy orbitals. - In tetrahedral complexes, the splitting of d-orbitals is relatively small compared to octahedral complexes, leading to a preference for high spin configurations. 4. **Reasoning Behind the Assertion**: - The reason provided states that "Δt = (4/9) Δ0". - Here, Δt represents the splitting energy in tetrahedral complexes, while Δ0 represents the splitting energy in octahedral complexes. - Since Δt is less than Δ0, the energy difference is not sufficient to favor low spin configurations, which require a larger splitting energy to promote electron pairing. 5. **Conclusion**: - Both the assertion and the reason are true. However, the reason does not directly explain why low spin configurations are rarely observed in tetrahedral complexes. Instead, it provides a factual basis for the energy splitting involved. - Therefore, the correct conclusion is that both statements are true, but the reason does not adequately support the assertion. ### Final Answer: Both the assertion and the reason are true, but the reason does not explain the assertion.

To solve the question regarding the assertion and reason related to tetrahedral complexes, we will analyze both statements step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that "In tetrahedral complexes, low spin configurations are rarely observed." - Tetrahedral complexes are typically formed by transition metals with a coordination number of 4, leading to sp³ hybridization. ...
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    NCERT FINGERTIPS ENGLISH|Exercise Warners Theory Of Coordination Compound|13 Videos
  • COORDINATION COMPOUNDS

    NCERT FINGERTIPS ENGLISH|Exercise Definition Of Some Important Terms Pertaining To Coordination Compounds|13 Videos
  • COORDINATION COMPOUNDS

    NCERT FINGERTIPS ENGLISH|Exercise NCERT EXEMPLAR PROBLEMS|14 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    NCERT FINGERTIPS ENGLISH|Exercise NCERT Exemplar|15 Videos
  • ELECTROCHEMISTRY

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos

Similar Questions

Explore conceptually related problems

Low spin configuration are rarely observed in tetrahedral coordination entity formation. Explain.

Why are low spin tetrahedral complexes not formed ?

Why are low spin tetrahedral complexes not formed ?

Assertion : A transistor amplifier in common emitter configuration has a low input impedence. Reason : The base to emitter region is forward biased.

Assertion : Inner orbital complexes are low spin complexes . Reason : In low spin complexes , inner d-orbital (3d) is used in hybridisation .

Consider the following satements : S_(1): Generally square planare complexes show geometrical isomerism but do not exhibit optical isomerism because thy do not possess plane of symmetry . S_(2): Delta_(t)=(4)/(9)Delta_(0) S_(3) : In octahedral complexes each electron entering teh t_(2g) orbitals stabilizes the complex ion by 0.4 Delta_(0) and each electron entering teh e_(g) orbital destabilizes the complex by an amount of 0.6 Delta_(0) Select the correct statement from the codes given below.

Assertion:- Reversible process and a cyclic process are the same type of processes. Reason:- DeltaH_("cylic") and DeltaE_("cylic") are zero.

Assertion : When helium is allowed to expands into vacuum, heating effect is observed. Reason : The inversion temperature of helium is very low.

CFSE(Delta_(0)) for metal ion in d^7 configuration in presence of strong ligand field is