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Assertion : K(2)[Ni(EDTA)] is more stabl...

Assertion : `K_(2)[Ni(EDTA)]` is more stable than `K_(3)[Al(C_(2)O_(4))_(3)]`.
Reason : Ni is a transition element while Al is a non-transition element .

A

If both Assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false

D

if both assertion and reason are false

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the stability of the coordination compounds \( K_2[Ni(EDTA)] \) and \( K_3[Al(C_2O_4)_3] \), we will analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Compounds**: - \( K_2[Ni(EDTA)] \): This compound consists of nickel (Ni) coordinated with EDTA (ethylenediaminetetraacetic acid), which is a hexadentate ligand. This means it can form multiple bonds with the metal ion. - \( K_3[Al(C_2O_4)_3] \): This compound consists of aluminum (Al) coordinated with oxalate ions (C2O4), which are bidentate ligands. 2. **Stability of Coordination Compounds**: - The stability of coordination compounds is often influenced by the number of coordination sites occupied by ligands. More coordination sites typically lead to greater stability due to the chelate effect. - In \( K_2[Ni(EDTA)] \), the EDTA ligand can form six bonds with nickel, leading to a very stable chelate complex. - In contrast, \( K_3[Al(C_2O_4)_3] \) has three bidentate oxalate ligands, which can form a maximum of six bonds, but the overall stability is generally lower than that of a complex with a hexadentate ligand like EDTA. 3. **Evaluating the Assertion**: - The assertion states that \( K_2[Ni(EDTA)] \) is more stable than \( K_3[Al(C_2O_4)_3] \). Given that EDTA forms a stronger chelate complex than oxalate, this assertion is **true**. 4. **Evaluating the Reason**: - The reason states that nickel is a transition element while aluminum is a non-transition element. While it is true that nickel is a transition metal and aluminum is not, this fact alone does not adequately explain the difference in stability between the two complexes. - The stability difference is primarily due to the nature of the ligands (EDTA vs. oxalate) and the chelate effect, rather than solely the classification of the metal ions. 5. **Conclusion**: - The assertion is true, but the reason provided does not correctly explain the assertion. Therefore, we conclude that while both statements are true, the reason is not a valid explanation for the assertion. ### Final Answer: - The assertion is true, and the reason is true but does not explain the assertion.

To solve the question regarding the stability of the coordination compounds \( K_2[Ni(EDTA)] \) and \( K_3[Al(C_2O_4)_3] \), we will analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Compounds**: - \( K_2[Ni(EDTA)] \): This compound consists of nickel (Ni) coordinated with EDTA (ethylenediaminetetraacetic acid), which is a hexadentate ligand. This means it can form multiple bonds with the metal ion. - \( K_3[Al(C_2O_4)_3] \): This compound consists of aluminum (Al) coordinated with oxalate ions (C2O4), which are bidentate ligands. ...
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