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An alkyl halide, RX reacts with KCN to g...

An alkyl halide, RX reacts with KCN to give propane nitrile. RX is

A

`C_3H_7Br`

B

`C_4H_9Br`

C

`C_2H_5Br`

D

`C_5H_(11)Br`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the alkyl halide (RX) that reacts with KCN to produce propane nitrile (C3H7CN), we can follow these steps: ### Step 1: Understand the Product The product given is propane nitrile, which has the molecular formula C3H7CN. This indicates that the compound has three carbon atoms (C3) and a nitrile functional group (CN). ### Step 2: Analyze the Reaction When an alkyl halide (RX) reacts with KCN, the KCN acts as a nucleophile. The nucleophile attacks the carbon atom that is bonded to the halogen (X) in the alkyl halide, leading to the substitution of the halogen with the cyanide group (CN). ### Step 3: Determine the Structure of the Alkyl Halide Since the product is propane nitrile (C3H7CN), we need to find an alkyl halide that, when reacted with KCN, will yield this product. The alkyl halide must have two carbon atoms (C2) because the reaction will add one carbon from KCN to the two carbons in the alkyl halide to form the three-carbon product. ### Step 4: Evaluate the Options Let's evaluate the given options: 1. **C3H7Br**: This would yield a four-carbon product (C4H9CN) when reacted with KCN. 2. **C4H9Br**: This would yield a five-carbon product (C5H11CN) when reacted with KCN. 3. **C2H5Br**: This would yield propane nitrile (C3H7CN) when reacted with KCN. 4. **C5H11Br**: This would yield a six-carbon product (C6H13CN) when reacted with KCN. ### Step 5: Identify the Correct Alkyl Halide The only option that, when reacted with KCN, produces propane nitrile (C3H7CN) is **C2H5Br**. Therefore, the correct answer is: **RX = C2H5Br** ### Final Answer The alkyl halide RX that reacts with KCN to give propane nitrile is **C2H5Br**. ---

To determine the alkyl halide (RX) that reacts with KCN to produce propane nitrile (C3H7CN), we can follow these steps: ### Step 1: Understand the Product The product given is propane nitrile, which has the molecular formula C3H7CN. This indicates that the compound has three carbon atoms (C3) and a nitrile functional group (CN). ### Step 2: Analyze the Reaction When an alkyl halide (RX) reacts with KCN, the KCN acts as a nucleophile. The nucleophile attacks the carbon atom that is bonded to the halogen (X) in the alkyl halide, leading to the substitution of the halogen with the cyanide group (CN). ...
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NCERT FINGERTIPS ENGLISH-HALOALKANES AND HALOARENES-Chemical reactions
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  2. The alkyl halide is converted into an alcohol by

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  3. An alkyl halide, RX reacts with KCN to give propane nitrile. RX is

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  4. In S(N^2) reactions the sequence of bond breaking and bond formation i...

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  5. Which of the following statement is not correct about S(N^2) reactions...

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  6. In the reaction given below: Which of the following statements is...

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  7. Tertiary alkyl halide are practially inert to substitution by SN^(2) ...

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  8. Among the choices of alkyl bromide , the least reactive bromide in a ...

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  9. Arrange the following compounds in order of their reactivity towards S...

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  10. Which of the following haloalkanes is most reactive?

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  11. Which of the following reactions does not take place?

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  12. Consider the following bromides: The correct order of S(N^1) reac...

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  13. Which of the following statement regarding S(N)1 reaction shown by alk...

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  14. Consider the following reaction: C6H5-underset(H)underset(|)overset(...

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  15. Which one of the following chlorohydrocarbons readily undergoes solvol...

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  16. Which of the following is the most reactive towards nucleophilic subst...

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  17. S(N^1) reaction is fastest in

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  18. Which of the following alkyl halides is hydrolysed by S(N^(1)) mechani...

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  19. Which of the following will give enantiomeric pair on reaction with wa...

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  20. Which of the following is most reactive towards aqueous NaOH?

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