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Which of the following will give enantio...

Which of the following will give enantiomeric pair on reaction with water due to presence of asymeteric carbon atom?

A

`C_2H_5-underset(C_2H_5)underset(|)overset(C_2H_5)overset(|)C-Br`

B

`C_2H_5-underset(CH_3)underset(|)overset(C_2H_5)overset(|)C-Cl`

C

`C_2H_5-underset(CH_3)underset(|)overset(H)overset(|)C-I`

D

`CH_3-underset(C_2H_5)underset(|)overset(CH_3)overset(|)C-Br`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given options will yield an enantiomeric pair upon reaction with water due to the presence of an asymmetric carbon atom, we can follow these steps: ### Step 1: Understand Key Concepts - **Enantiomeric Pair**: These are molecules that are non-superimposable mirror images of each other. They typically arise from chiral centers (asymmetric carbon atoms). - **Asymmetric Carbon Atom**: A carbon atom that is bonded to four different groups, making it chiral. ### Step 2: Analyze Each Option We will evaluate each option to identify if it contains an asymmetric carbon atom. #### Option A: - Structure: Carbon attached to three ethyl groups and one bromide group. - Analysis: The three ethyl groups are identical. Therefore, this carbon is not asymmetric and cannot form an enantiomeric pair. #### Option B: - Structure: Carbon attached to two ethyl groups and one methyl group. - Analysis: The two ethyl groups are identical. Thus, this carbon is not asymmetric and cannot form an enantiomeric pair. #### Option C: - Structure: Carbon attached to one hydrogen, one ethyl group, one methyl group, and one iodide group. - Analysis: All four groups attached to this carbon are different (H, C2H5, CH3, I). Therefore, this carbon is asymmetric and can form an enantiomeric pair upon reaction with water. #### Option D: - Structure: Carbon attached to two methyl groups and one bromide group. - Analysis: The two methyl groups are identical. Hence, this carbon is not asymmetric and cannot form an enantiomeric pair. ### Step 3: Conclusion Based on the analysis, only **Option C** has an asymmetric carbon atom and will yield an enantiomeric pair upon reaction with water. ### Final Answer: The correct option is **C**. ---

To determine which of the given options will yield an enantiomeric pair upon reaction with water due to the presence of an asymmetric carbon atom, we can follow these steps: ### Step 1: Understand Key Concepts - **Enantiomeric Pair**: These are molecules that are non-superimposable mirror images of each other. They typically arise from chiral centers (asymmetric carbon atoms). - **Asymmetric Carbon Atom**: A carbon atom that is bonded to four different groups, making it chiral. ### Step 2: Analyze Each Option We will evaluate each option to identify if it contains an asymmetric carbon atom. ...
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NCERT FINGERTIPS ENGLISH-HALOALKANES AND HALOARENES-Chemical reactions
  1. S(N^1) reaction is fastest in

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  2. Which of the following alkyl halides is hydrolysed by S(N^(1)) mechani...

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  3. Which of the following will give enantiomeric pair on reaction with wa...

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  4. Which of the following is most reactive towards aqueous NaOH?

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  5. In the following pairs of halogen compounds, which compounds undergoes...

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  6. Which of the following haloalkanes reacts with aqueous KOH most easily...

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  7. Which alkyl halide exhibits complete racemisation in S(N^1) reaction?

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  8. The order of reactivity of various alkyl halides towards nucleophilic ...

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  9. Alkyl halides are formed when thionyl chloride and are refluxed in pr...

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  10. 2-Bromo-3,3- dimethylbutane on reaction with aqueous KOH yields X as t...

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  11. Among the isomers of C5H11Cl, the one which is chiral is (i) 2,2-Dim...

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  12. Ethylene dichloride and ethylidene chloride are isomeric compounds. Th...

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  13. The major product formed in the following reaction is CH3-underset(H...

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  14. Which of the following reactions will give the major and minor product...

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  15. The products (A) and (B) are respectively. (i) CH3-underset(Br)under...

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  16. A mixture of 1-chloropropane and 2-chloropropane when treated with alc...

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  17. Consider the following reaction and identify X and Y. {:(CH3CH2CH2Io...

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  18. An alkyl halide with molecular formula C6H(13)Br on dehyrohalogenation...

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  19. Arrange the following alkyl halides in order of dehydrohalgenation, C2...

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  20. 2-Chloro-2-methylpropane on reaction with aqueous KOH gives X as the m...

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