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Which of the following reactions will gi...

Which of the following reactions will give the major and minor products?
`CH_3-CH_2underset(Br)underset(|)(CH)-CH_3underset("heat")overset(alc. KOH)toCH_3-underset((A))(CH=CH)+underset((B))(CH_3-CH_2-CH=CH_2)`

A

(A) is major product and (B) is minor product.

B

(A) is minor product and (B) is major product.

C

Both (A) and (B) are major products.

D

Only (B) is formed and (A) is not formed.

Text Solution

AI Generated Solution

The correct Answer is:
To determine the major and minor products of the reaction of 2-bromobutane with alcoholic KOH, we can follow these steps: ### Step 1: Identify the Reactant The reactant is 2-bromobutane, which has the following structure: \[ CH_3-CH_2-CH(Br)-CH_3 \] ### Step 2: Understand the Reaction Conditions The reaction is carried out in the presence of alcoholic KOH. Alcoholic KOH acts as a strong base and promotes elimination reactions (dehydrohalogenation) rather than substitution reactions. ### Step 3: Determine the Mechanism In this reaction, the base (KOH) will abstract a beta-hydrogen (a hydrogen atom from the carbon adjacent to the carbon bearing the bromine atom). This results in the elimination of HBr and the formation of a double bond. ### Step 4: Identify Beta-Hydrogens For 2-bromobutane: - The beta-carbons are the ones adjacent to the carbon with the bromine. - The beta-hydrogens that can be removed are located on the carbons adjacent to the carbon with the Br. ### Step 5: Possible Products 1. **Elimination of a beta-hydrogen from the carbon with two methyl groups (C1)** leads to: - **But-2-ene** (more substituted alkene) - Structure: \( CH_3-CH=CH-CH_3 \) 2. **Elimination of a beta-hydrogen from the carbon with one methyl group (C2)** leads to: - **But-1-ene** (less substituted alkene) - Structure: \( CH_3-CH_2-CH=CH_2 \) ### Step 6: Determine Major and Minor Products According to Zaitsev's rule (or Saytzeff's rule), the more substituted alkene is favored as the major product. In this case: - **But-2-ene** (product A) is more substituted (it has two alkyl groups attached to the double bond). - **But-1-ene** (product B) is less substituted (it has only one alkyl group attached to the double bond). ### Conclusion - **Major Product (A)**: But-2-ene - **Minor Product (B)**: But-1-ene ### Final Answer The major product is but-2-ene (A) and the minor product is but-1-ene (B). ---

To determine the major and minor products of the reaction of 2-bromobutane with alcoholic KOH, we can follow these steps: ### Step 1: Identify the Reactant The reactant is 2-bromobutane, which has the following structure: \[ CH_3-CH_2-CH(Br)-CH_3 \] ### Step 2: Understand the Reaction Conditions The reaction is carried out in the presence of alcoholic KOH. Alcoholic KOH acts as a strong base and promotes elimination reactions (dehydrohalogenation) rather than substitution reactions. ...
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