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A mixture of 1-chloropropane and 2-chlor...

A mixture of `1-`chloropropane and `2-`chloropropane when treated with alcoholic `KOH`, it gives

A

prop-1-ene

B

prop-2-ene

C

a mixture of prop-1-ene and prop-2 ene

D

propanol.

Text Solution

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The correct Answer is:
To solve the problem of what a mixture of 1-chloropropane and 2-chloropropane gives when treated with alcoholic KOH, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Compounds**: - The first compound is **1-chloropropane (C3H7Cl)**, which has the structure: \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{Cl} \] - The second compound is **2-chloropropane (C3H7Cl)**, which has the structure: \[ \text{CH}_3\text{CHCl}\text{CH}_3 \] 2. **Understand the Reaction with Alcoholic KOH**: - Alcoholic KOH promotes **elimination reactions** (specifically, beta-elimination). This means that we will be removing a hydrogen atom from the beta carbon (the carbon adjacent to the carbon with the leaving group, Cl) and the leaving group (Cl) itself. 3. **Reaction of 1-Chloropropane**: - For **1-chloropropane**, the beta hydrogens are on the second carbon (CH2). When we remove one of these beta hydrogens, the reaction can be represented as follows: \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{Cl} + \text{KOH (alc)} \rightarrow \text{CH}_3\text{CH}=\text{CH}_2 + \text{KCl} + \text{H}_2\text{O} \] - The product formed is **prop-1-ene** (or simply propene). 4. **Reaction of 2-Chloropropane**: - For **2-chloropropane**, the beta hydrogens are on both adjacent carbons. The reaction can be represented as: \[ \text{CH}_3\text{CHCl}\text{CH}_3 + \text{KOH (alc)} \rightarrow \text{CH}_3\text{CH}=\text{CH}_2 + \text{KCl} + \text{H}_2\text{O} \] - Again, the product formed is **prop-1-ene**. 5. **Conclusion**: - Both reactions yield the same product, which is **prop-1-ene**. Therefore, when a mixture of 1-chloropropane and 2-chloropropane is treated with alcoholic KOH, the product is **prop-1-ene**. ### Final Answer: The mixture of 1-chloropropane and 2-chloropropane when treated with alcoholic KOH gives **prop-1-ene**. ---

To solve the problem of what a mixture of 1-chloropropane and 2-chloropropane gives when treated with alcoholic KOH, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Compounds**: - The first compound is **1-chloropropane (C3H7Cl)**, which has the structure: \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{Cl} ...
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