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2-Chloro-2-methylpropane on reaction wit...

2-Chloro-2-methylpropane on reaction with aqueous KOH gives X as the major product. X is

A

but-2-ene

B

2-methylbut-1-ene

C

2-methylprop-1-ene

D

2-methylbutan-2-ol

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The correct Answer is:
To solve the question regarding the reaction of 2-chloro-2-methylpropane with aqueous KOH, we will follow these steps: ### Step 1: Identify the structure of 2-chloro-2-methylpropane 2-chloro-2-methylpropane is a tertiary haloalkane. Its structure can be represented as follows: ``` CH3 | CH3-C-Cl | CH3 ``` ### Step 2: Understand the reaction conditions When 2-chloro-2-methylpropane reacts with aqueous KOH, it undergoes an elimination reaction. Given that it is a tertiary halide, the reaction will favor an E2 elimination mechanism. ### Step 3: Identify the elimination mechanism In the E2 mechanism, a base (in this case, KOH) abstracts a beta-hydrogen while the leaving group (Cl) departs simultaneously. The beta-hydrogens are those attached to the carbon atoms adjacent to the carbon bearing the chlorine atom. ### Step 4: Determine the beta-hydrogens In the structure of 2-chloro-2-methylpropane, there are three beta-hydrogens available for elimination: - The beta carbons are the ones adjacent to the carbon with the chlorine atom. ### Step 5: Perform the elimination When a beta-hydrogen is removed, the electrons from the C-H bond will form a double bond between the alpha carbon (the one with the chlorine) and the beta carbon from which the hydrogen was removed. The chlorine will leave as Cl⁻. ### Step 6: Write the product The major product formed from this elimination will be 2-methylpropene (or 2-methylprop-1-ene), which can be represented as: ``` CH3 | CH3-C=CH2 ``` ### Step 7: Name the product The product is named 2-methylprop-1-ene. ### Conclusion Thus, the major product X formed from the reaction of 2-chloro-2-methylpropane with aqueous KOH is **2-methylprop-1-ene**. ---

To solve the question regarding the reaction of 2-chloro-2-methylpropane with aqueous KOH, we will follow these steps: ### Step 1: Identify the structure of 2-chloro-2-methylpropane 2-chloro-2-methylpropane is a tertiary haloalkane. Its structure can be represented as follows: ``` CH3 | ...
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NCERT FINGERTIPS ENGLISH-HALOALKANES AND HALOARENES-Chemical reactions
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  2. Arrange the following alkyl halides in order of dehydrohalgenation, C2...

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  3. 2-Chloro-2-methylpropane on reaction with aqueous KOH gives X as the m...

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  4. Which of the following products as shown by the dehydrohalogenation of...

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  5. Match the reactions given in column I with the type of reaction mentio...

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  6. An alkyl chloride produces a single alkene on reaction with sodium eth...

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  7. Trans-2-phenyl-1-bromocyclopentane on reaction with alcoholic KOH prod...

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  8. Identify (Z) in the following reaction series, C2H5Ioverset("Alcoho...

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  9. The ease of dehydrohalogenation of alkyl halide with alcoholic KOH is-

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  10. Elimination of bromine from 2-bromobutane results in the formation of ...

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  11. Which of the following products does not match correctly with the reac...

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  12. In the reaction , CH(3)-underset(Br)underset(|)(CH)-CH(3)overset(alc...

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  13. Grignard reagent, a very useful starting compound for a number of orga...

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  14. The order of reactivities of methyl halide in the formation of Grignar...

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  15. Identify the products X and Y in the given reaction, CH3-underset(Br...

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  16. Alkyl halides react with metallic sodium in dry ether producing

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  17. On treating a mixture of two alkyl halides with sodium metal in dry et...

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  18. Chlorobenzene on treatment with sodium in dry ether gives diphenyl. Th...

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  19. Primary alkyl halide C4H9Br (X) reacts with alc. KOH to give compound ...

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  20. The main difference in C-X bond of a haloalkane and a haloarene is

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