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Identify (Z) in the following reaction s...

Identify (Z) in the following reaction series,
`C_2H_5Ioverset("Alcoholic")underset("KOH")rarr(X)overset(Br_2)rarr (Y)overset(KCN)rarr (Z)`

A

`CH_3-CH_2-CN`

B

`underset(CN)underset(|)CH_2-underset(CN)underset(|)CH_2`

C

`underset(Br)underset(|)CH_2-underset(CN)underset(|)CH_2`

D

`underset(Br)underset(|)CH=underset(CN)underset(|)"CH"`

Text Solution

AI Generated Solution

The correct Answer is:
To identify compound (Z) in the reaction series provided, we will analyze each step of the reaction: ### Step 1: Reaction of C2H5I with Alcoholic KOH - The starting compound is **C2H5I** (ethyl iodide). - When ethyl iodide reacts with alcoholic KOH, it undergoes **beta elimination** (dehydrohalogenation), which involves the removal of HI (hydrogen iodide). - The reaction can be represented as: \[ C_2H_5I + KOH \rightarrow C_2H4 + HI \] - The product formed (X) is **ethene (C2H4)**. ### Step 2: Reaction of Ethene with Br2 - The next step involves the reaction of ethene with bromine (Br2). - Ethene undergoes an **electrophilic addition** reaction with bromine, resulting in the formation of **1,2-dibromoethane** (Y). - The reaction can be represented as: \[ C_2H4 + Br_2 \rightarrow C_2H4Br_2 \] - The product formed (Y) is **1,2-dibromoethane** (C2H4Br2). ### Step 3: Reaction of 1,2-Dibromoethane with KCN - Finally, 1,2-dibromoethane reacts with potassium cyanide (KCN). - In this reaction, the bromine atoms are substituted by cyanide groups (–CN), as cyanide is a good nucleophile. - The reaction can be represented as: \[ C_2H4Br_2 + 2 KCN \rightarrow C_2H4(CN)_2 + 2 KBr \] - The product formed (Z) is **1,2-dicyanoethane** (C2H4(CN)2). ### Conclusion - Therefore, the final compound (Z) is **1,2-dicyanoethane**. ### Summary of Compounds: - **X**: Ethene (C2H4) - **Y**: 1,2-Dibromoethane (C2H4Br2) - **Z**: 1,2-Dicyanoethane (C2H4(CN)2)

To identify compound (Z) in the reaction series provided, we will analyze each step of the reaction: ### Step 1: Reaction of C2H5I with Alcoholic KOH - The starting compound is **C2H5I** (ethyl iodide). - When ethyl iodide reacts with alcoholic KOH, it undergoes **beta elimination** (dehydrohalogenation), which involves the removal of HI (hydrogen iodide). - The reaction can be represented as: \[ C_2H_5I + KOH \rightarrow C_2H4 + HI ...
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NCERT FINGERTIPS ENGLISH-HALOALKANES AND HALOARENES-Chemical reactions
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  3. Identify (Z) in the following reaction series, C2H5Ioverset("Alcoho...

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  4. The ease of dehydrohalogenation of alkyl halide with alcoholic KOH is-

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  5. Elimination of bromine from 2-bromobutane results in the formation of ...

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  6. Which of the following products does not match correctly with the reac...

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  7. In the reaction , CH(3)-underset(Br)underset(|)(CH)-CH(3)overset(alc...

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  8. Grignard reagent, a very useful starting compound for a number of orga...

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  9. The order of reactivities of methyl halide in the formation of Grignar...

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  10. Identify the products X and Y in the given reaction, CH3-underset(Br...

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  12. On treating a mixture of two alkyl halides with sodium metal in dry et...

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  14. Primary alkyl halide C4H9Br (X) reacts with alc. KOH to give compound ...

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  15. The main difference in C-X bond of a haloalkane and a haloarene is

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  16. Aryl halides are less reactive towards nucleophilic substitution react...

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  17. Chlorobenzene can be converted into phenol by heating in aqueous sodi...

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  18. Match the column I with column II and mark the appropriate choice.

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  19. The end product (Q) in the following sequence of reaction is

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  20. Which of the following reactions is not correctly matched ?

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