Home
Class 12
CHEMISTRY
Elimination of bromine from 2-bromobutan...

Elimination of bromine from 2-bromobutane results in the formation of
(i)equimolar mixture of 1 and 2-butane
(ii)predominantly2-butene
(iii)predominantly 1-butene
(iv)predominantly 2-butyne.

A

equimolar mixture of 1 and 2 butene

B

predominantly 1-butene

C

predominantly 1-butene

D

predominantly 2-butyne

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the elimination of bromine from 2-bromobutane, we can follow these steps: ### Step 1: Identify the Structure of 2-Bromobutane 2-bromobutane is a four-carbon alkane with a bromine atom attached to the second carbon. The structure can be represented as follows: ``` CH3-CH(Br)-CH2-CH3 ``` ### Step 2: Understand the Elimination Reaction In an elimination reaction, a small group (in this case, bromine) is removed from a larger molecule, leading to the formation of a double bond. The reaction typically involves the removal of a hydrogen atom from a beta carbon and the halogen from the alpha carbon. ### Step 3: Identify Alpha and Beta Carbons In 2-bromobutane: - The alpha carbon is the one attached to the bromine (C2). - The beta carbons are the carbons adjacent to the alpha carbon (C1 and C3). ### Step 4: Use a Strong Base for Elimination When treated with a strong base like alcoholic KOH, the base will abstract a hydrogen atom from one of the beta carbons, leading to the formation of an alkene. ### Step 5: Determine Possible Products 1. **If H is removed from C1 (beta carbon)**: - The product formed will be 1-butene: ``` CH2=CH-CH2-CH3 (1-butene) ``` 2. **If H is removed from C3 (beta carbon)**: - The product formed will be 2-butene: ``` CH3-CH=CH-CH3 (2-butene) ``` ### Step 6: Apply Zaitsev's Rule According to Zaitsev's rule, the more substituted alkene is favored in elimination reactions. In this case: - 1-butene has one substituent (the double bond is at the end). - 2-butene has more substituents (the double bond is in the middle and is more stable). ### Step 7: Conclusion Since 2-butene is more substituted and therefore more stable than 1-butene, the predominant product of the elimination of bromine from 2-bromobutane will be predominantly 2-butene. ### Final Answer The correct option is (ii) predominantly 2-butene. ---

To solve the question regarding the elimination of bromine from 2-bromobutane, we can follow these steps: ### Step 1: Identify the Structure of 2-Bromobutane 2-bromobutane is a four-carbon alkane with a bromine atom attached to the second carbon. The structure can be represented as follows: ``` CH3-CH(Br)-CH2-CH3 ``` ...
Promotional Banner

Topper's Solved these Questions

  • HALOALKANES AND HALOARENES

    NCERT FINGERTIPS ENGLISH|Exercise Higher order thinking skills|8 Videos
  • HALOALKANES AND HALOARENES

    NCERT FINGERTIPS ENGLISH|Exercise Exemplar problems|24 Videos
  • HALOALKANES AND HALOARENES

    NCERT FINGERTIPS ENGLISH|Exercise Physical properties|7 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos
  • POLYMERS

    NCERT FINGERTIPS ENGLISH|Exercise NCERT Exemplar|9 Videos

Similar Questions

Explore conceptually related problems

Elimination of HBr from 2 bromobutane results in the formation of .

Convert : a. 1- Bromobutane to 2- bromobutane

The reaction of toluene with CI_(2) in presence of FeCI_(3) gives predominantly

The formation of 1,2-dibromoethane from ethene and bromine is an example of :

Assertion:2-Bromobutane on reaction with sodium ethoxide in ethanol gives 1-butene as a major product Reason:1-butene is more stable than 2-butene.

Conversion of 2-Butene into n-Butane

The number of stereoisomers obtained by bromination of trans-2-butene is :

What type of isomerism is shown by 1-butene and 2-butene?

Arrange the melting points of following compounds in decreasing order 1. n - butane 2. cis - 2- butene 3. trans -2- butene 4. 1 - butyne

NCERT FINGERTIPS ENGLISH-HALOALKANES AND HALOARENES-Chemical reactions
  1. Identify (Z) in the following reaction series, C2H5Ioverset("Alcoho...

    Text Solution

    |

  2. The ease of dehydrohalogenation of alkyl halide with alcoholic KOH is-

    Text Solution

    |

  3. Elimination of bromine from 2-bromobutane results in the formation of ...

    Text Solution

    |

  4. Which of the following products does not match correctly with the reac...

    Text Solution

    |

  5. In the reaction , CH(3)-underset(Br)underset(|)(CH)-CH(3)overset(alc...

    Text Solution

    |

  6. Grignard reagent, a very useful starting compound for a number of orga...

    Text Solution

    |

  7. The order of reactivities of methyl halide in the formation of Grignar...

    Text Solution

    |

  8. Identify the products X and Y in the given reaction, CH3-underset(Br...

    Text Solution

    |

  9. Alkyl halides react with metallic sodium in dry ether producing

    Text Solution

    |

  10. On treating a mixture of two alkyl halides with sodium metal in dry et...

    Text Solution

    |

  11. Chlorobenzene on treatment with sodium in dry ether gives diphenyl. Th...

    Text Solution

    |

  12. Primary alkyl halide C4H9Br (X) reacts with alc. KOH to give compound ...

    Text Solution

    |

  13. The main difference in C-X bond of a haloalkane and a haloarene is

    Text Solution

    |

  14. Aryl halides are less reactive towards nucleophilic substitution react...

    Text Solution

    |

  15. Chlorobenzene can be converted into phenol by heating in aqueous sodi...

    Text Solution

    |

  16. Match the column I with column II and mark the appropriate choice.

    Text Solution

    |

  17. The end product (Q) in the following sequence of reaction is

    Text Solution

    |

  18. Which of the following reactions is not correctly matched ?

    Text Solution

    |

  19. Chloroform is stored in dark coloured bottles. Explain in not more t...

    Text Solution

    |

  20. Triiodomethane has antiseptic property because of

    Text Solution

    |