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Assertion: Aryl halides are highly react...

Assertion: Aryl halides are highly reactive towards nucleophilic substitution reactions.
Reason: In case of halorenes, halogen atom is attached to sp hybridised carbon atom.

A

If both assertion and reason are true and reason Is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assetion is true but reason is false.

D

If both assertion and reason are false.

Text Solution

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The correct Answer is:
To solve the question regarding the assertion and reason about aryl halides and their reactivity towards nucleophilic substitution reactions, we can break it down step by step: ### Step 1: Analyze the Assertion The assertion states that "Aryl halides are highly reactive towards nucleophilic substitution reactions." - **Explanation**: Aryl halides, such as chlorobenzene, do not readily undergo nucleophilic substitution reactions. The presence of the aromatic ring stabilizes the molecule, making the carbon-halogen bond less reactive. Therefore, this assertion is **false**. ### Step 2: Analyze the Reason The reason states that "In case of haloarenes, the halogen atom is attached to sp hybridized carbon atom." - **Explanation**: In haloarenes, the carbon atom to which the halogen is attached is part of an aromatic system, which means it is sp² hybridized (not sp hybridized). The sp² hybridization arises because the carbon is bonded to two other carbons in the aromatic ring and has a double bond character with the halogen due to resonance. Thus, this reason is also **false**. ### Step 3: Conclusion Since both the assertion and the reason are false, the correct answer to the question is that both the assertion and reason are incorrect. ### Final Answer Both assertion and reason are false. ---

To solve the question regarding the assertion and reason about aryl halides and their reactivity towards nucleophilic substitution reactions, we can break it down step by step: ### Step 1: Analyze the Assertion The assertion states that "Aryl halides are highly reactive towards nucleophilic substitution reactions." - **Explanation**: Aryl halides, such as chlorobenzene, do not readily undergo nucleophilic substitution reactions. The presence of the aromatic ring stabilizes the molecule, making the carbon-halogen bond less reactive. Therefore, this assertion is **false**. ### Step 2: Analyze the Reason ...
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