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Complete the missing links . A overset...

Complete the missing links .
`A overset(CH_(3) MgBr)(to) B overset(H_(3)O^(+))(to) C`

A

`CH_3COCH_3 (CH_3)_3COMgBr, (CH_3)_3COH`

B

`CH_3COOH, (CH_3)CHOMgBr, CH_3CH_2OH`

C

`(CH_3COO)_2Ca, CH_3CH_2OMgBr, CH_2underset(OH)underset(|)"CH"-CH_3`

D

`CH_3COOCH_3, (CH_3)_3COMgBr,CH_3-underset(OH)underset(|)"CH"-CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify the compounds A, B, and C based on the reaction with Grignard's reagent (CH₃MgBr) and subsequent hydrolysis. ### Step-by-Step Solution: 1. **Identify Compound A:** - The question states that compound A reacts with Grignard's reagent. Given the context, we can deduce that compound A is likely a type of ether. - In this case, we can identify A as **dimethyl ether (CH₃OCH₃)**. 2. **Reaction with Grignard's Reagent:** - When dimethyl ether (A) reacts with Grignard's reagent (CH₃MgBr), the Grignard reagent acts as a nucleophile and attacks the ether. - This reaction leads to the formation of a new compound, which we can denote as B. The reaction can be represented as follows: \[ \text{CH}_3\text{OCH}_3 + \text{CH}_3\text{MgBr} \rightarrow \text{CH}_3\text{C(OMgBr)(CH}_3\text{)} \] - Here, B is a magnesium alkoxide, specifically **(CH₃)₂C(OMgBr)**. 3. **Hydrolysis of Compound B:** - The next step involves the hydrolysis of compound B in the presence of water (H₃O⁺). - During hydrolysis, the alkoxide reacts with water, leading to the formation of an alcohol. The hydrolysis can be represented as follows: \[ \text{(CH}_3\text{)}_2\text{C(OMgBr)} + \text{H}_3\text{O}^+ \rightarrow \text{(CH}_3\text{)}_2\text{C(OH)} + \text{MgBrOH} \] - The resulting compound C is a tertiary alcohol, specifically **tert-butyl alcohol (C(CH₃)₃OH)**. 4. **Final Summary:** - Therefore, the complete reaction sequence is: - A: Dimethyl ether (CH₃OCH₃) - B: (CH₃)₂C(OMgBr) - C: Tert-butyl alcohol (C(CH₃)₃OH) ### Final Answer: - A: Dimethyl ether (CH₃OCH₃) - B: (CH₃)₂C(OMgBr) - C: Tert-butyl alcohol (C(CH₃)₃OH)

To solve the question, we need to identify the compounds A, B, and C based on the reaction with Grignard's reagent (CH₃MgBr) and subsequent hydrolysis. ### Step-by-Step Solution: 1. **Identify Compound A:** - The question states that compound A reacts with Grignard's reagent. Given the context, we can deduce that compound A is likely a type of ether. - In this case, we can identify A as **dimethyl ether (CH₃OCH₃)**. ...
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