Home
Class 12
CHEMISTRY
Consider the following reaction sequence...

Consider the following reaction sequence ,
`CH_(3)CH(OH)CH_(3) overset("Conc" H_(2)SO_(4))underset("Heat")(to) X underset(H_(2)O) overset("dil." H_(2)SO_(4))(to) Y`
X and Y in the reaction respectively are

A

`CH_3 CH = CH_(2) , CH_(3)CH(OH)CH_(3)`

B

`CH_(3)CH = CHCH_(3) , CH_(3)CH_(2)CH_(2)OH`

C

`CH_(3)CH_(2)CH = CH_(2) , CH_(3) , CH_(2)CH_(2) OH`

D

`CH_(3) CH_(2) CH_(2) CH_(3) , CH_(3)CH(OH)CH_(2)CH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the reaction sequence given in the question, we will break it down step by step. ### Step 1: Identify the starting compound The starting compound is 2-propanol, which can be represented as: \[ \text{CH}_3\text{CH(OH)CH}_3 \] ### Step 2: React with concentrated sulfuric acid (H₂SO₄) When 2-propanol reacts with concentrated sulfuric acid and heat, it undergoes dehydration. The mechanism involves the following: - The hydroxyl group (–OH) is protonated by H⁺ from H₂SO₄, making it a better leaving group. - Water (H₂O) is eliminated, forming a carbocation. The reaction can be represented as: \[ \text{CH}_3\text{CH(OH)CH}_3 \xrightarrow{\text{Conc. H}_2\text{SO}_4, \text{Heat}} \text{CH}_3\text{C}^+\text{HCH}_3 \] ### Step 3: Formation of the alkene The carbocation formed can lose a hydrogen atom to form an alkene. The possible product is propene: \[ \text{CH}_3\text{C}^+\text{HCH}_3 \rightarrow \text{CH}_3\text{CH}=\text{CH}_2 \] Thus, the product X is: \[ \text{X} = \text{CH}_3\text{CH}=\text{CH}_2 \quad (\text{Propene}) \] ### Step 4: React with dilute sulfuric acid (H₂SO₄) Now, we take the alkene (propene) and react it with dilute sulfuric acid. In this case, the reaction involves hydration: - The H⁺ from H₂SO₄ adds to one of the carbons of the double bond, following Markovnikov's rule, which states that the hydrogen will add to the carbon with more hydrogens already attached. - Water (H₂O) acts as a nucleophile and attacks the carbocation formed. The reaction can be represented as: \[ \text{CH}_3\text{CH}=\text{CH}_2 \xrightarrow{\text{dil. H}_2\text{SO}_4} \text{CH}_3\text{CH(OH)CH}_3 \] ### Step 5: Identify the final product Y The final product Y is 2-propanol: \[ \text{Y} = \text{CH}_3\text{CH(OH)CH}_3 \] ### Conclusion Thus, the products X and Y in the reaction sequence are: - **X**: Propene (\( \text{CH}_3\text{CH}=\text{CH}_2 \)) - **Y**: 2-Propanol (\( \text{CH}_3\text{CH(OH)CH}_3 \)) ### Summary of the Answer - **X**: Propene (\( \text{CH}_3\text{CH}=\text{CH}_2 \)) - **Y**: 2-Propanol (\( \text{CH}_3\text{CH(OH)CH}_3 \))

To solve the reaction sequence given in the question, we will break it down step by step. ### Step 1: Identify the starting compound The starting compound is 2-propanol, which can be represented as: \[ \text{CH}_3\text{CH(OH)CH}_3 \] ### Step 2: React with concentrated sulfuric acid (H₂SO₄) When 2-propanol reacts with concentrated sulfuric acid and heat, it undergoes dehydration. The mechanism involves the following: ...
Promotional Banner

Topper's Solved these Questions

  • ALCOHOLS,PHENOLS AND ETHERS

    NCERT FINGERTIPS ENGLISH|Exercise HOTS|7 Videos
  • ALCOHOLS,PHENOLS AND ETHERS

    NCERT FINGERTIPS ENGLISH|Exercise EXEMPLAR PROBLEMS|14 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos

Similar Questions

Explore conceptually related problems

In this reaction , (CH_(3))_(3) C - CH_(2)OH overset("Conc." H_(2)SO_(4))underset(170^(@)C)(to) X X is

Complete the following reactions : CH_3COOH +C_2H_5OH overset(conc.)underset(H_2SO_4) rarr

Consider the following reaction sequence, CH_(3)C-= CH overset(aq.H_(2)SO_(4))underset(Hg SO_(4))rarr A overset(PCl_(5))underset(Heat)rarrB The products (A) and (B) are, respectively,

The main product of the following reaction is C_(6)H_(5)CH_(2)(OH)CH(CH_(3))_(2)overset(Conc.H_(2)SO_(4))rarr ?

In the following reaction sequence, CH_(3) - underset((X))underset(OH)underset(|)(C)H-CH_(3) overset([O])(to) Y overset(CH_(3)MgBr)underset(H^(+)// H_(2)O)(to) Z Z is

CH_(3)CH_(2)CH_(2)OH underset(170^(@)C)overset(conc." "H_(2)SO_(4))to A underset(500^(@)C)overset(Cl_(2))toB . A and B. are

Study the following sequence of reaction and identify the product (Y). CH_(3)CHO +HCHO overset("dil."NaOH)underset("heat") to X overset(HCN) underset(H_(3)O^(+)) to Y

CH_(3)-overset(CH_(3))overset(|)(CH)-NO_(2) underset(at 0^(@)C)overset(NaNO_(2)+H_(2)SO_(4))(rarr)(A) . (A) is:

CH_2Ounderset(H_3O^(o+))overset(CHD_2MgI)toX underset(Delta)overset(Conc.H_2SO_4)toY In the above reaction compound X & Y respectively will be