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In this reaction , (CH(3))(3) C - CH(2)O...

In this reaction , `(CH_(3))_(3) C - CH_(2)OH overset("Conc." H_(2)SO_(4))underset(170^(@)C)(to) X`
X is

A

`(CH_3)_2C=CHCH_3`

B

`CH_3-=CH`

C

`(CH_3)_2CHCH_2CH_3`

D

`CH_3-CH_2-underset(CH_3)underset(|)C=CH_2`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reaction of the given tertiary alcohol, `(CH₃)₃C-CH₂OH`, when treated with concentrated sulfuric acid (H₂SO₄) at a temperature of 170°C. The goal is to determine the product X formed in this reaction. ### Step-by-Step Solution: 1. **Identify the Reactant:** The reactant is `(CH₃)₃C-CH₂OH`, which is a tertiary alcohol. The structure can be represented as: ``` CH₃ | CH₃-C-CH₂-OH | CH₃ ``` 2. **Understand the Role of Concentrated H₂SO₄:** Concentrated sulfuric acid acts as a dehydrating agent. It removes water (H₂O) from the alcohol, leading to the formation of a carbocation intermediate. 3. **Formation of the Carbocation:** When the alcohol is treated with H₂SO₄, the hydroxyl group (OH) is protonated, making it a better leaving group. The reaction proceeds as follows: - Protonation of the OH group leads to the formation of an oxonium ion (OH₂⁺). - The loss of water (H₂O) from the oxonium ion generates a carbocation. 4. **Determine the Stability of the Carbocation:** The initial carbocation formed would be a primary carbocation, which is less stable. To achieve a more stable carbocation, a methyl shift occurs: - A methyl group from the adjacent carbon shifts to the positively charged carbon, resulting in a more stable tertiary carbocation. 5. **Final Product Formation:** The stable tertiary carbocation can then lose a proton (H⁺) to form an alkene. The elimination of H⁺ leads to the formation of the double bond: - The resulting alkene structure will be: ``` CH₃ | CH₃-C=CH-CH₃ | CH₃ ``` This can be represented as 2-methylbut-2-ene. 6. **Conclusion:** The product X formed from the reaction of `(CH₃)₃C-CH₂OH` with concentrated H₂SO₄ at 170°C is 2-methylbut-2-ene. ### Final Answer: **X is 2-methylbut-2-ene.**
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