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Which of the following alcohols on dehyd...

Which of the following alcohols on dehydration with conc. `H_(2)SO_(4)` will yield But-2-ene ?

A

p-`O_(2) N C_(6)H_(4) CH(OH)CH_(3)`

B

p-`ClC_(6)H_(4)CH (OH) CH_(3)`

C

`p-CH_(3)OC_(6) H_(4) CH (OH) CH_(3)`

D

`C_(6)H_(5)CH (OH) CH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which alcohol will yield But-2-ene upon dehydration with concentrated sulfuric acid (H₂SO₄), we need to analyze the structure of the alcohols provided in the options. ### Step-by-Step Solution: 1. **Understanding Dehydration Reaction**: Dehydration of alcohols involves the removal of a water molecule (H₂O) from the alcohol, leading to the formation of alkenes. The reaction typically requires an acid catalyst, such as concentrated sulfuric acid. 2. **Identify the Alcohols**: Let's assume the options provided include various alcohols, including butan-1-ol, butan-2-ol, tert-butyl alcohol, and others. We need to focus on butan-2-ol (2-butanol) for this specific question. 3. **Structure of Butan-2-ol**: Butan-2-ol has the following structure: \[ CH₃-CHOH-CH₂-CH₃ \] It is a secondary alcohol, which means the hydroxyl (-OH) group is attached to a carbon that is connected to two other carbon atoms. 4. **Dehydration Reaction of Butan-2-ol**: When butan-2-ol is treated with concentrated H₂SO₄ and heated, the dehydration reaction proceeds as follows: \[ CH₃-CHOH-CH₂-CH₃ \xrightarrow{H₂SO₄, \text{heat}} CH₃-CH=CH-CH₃ + H₂O \] This results in the formation of But-2-ene (CH₃-CH=CH-CH₃). 5. **Conclusion**: Therefore, the alcohol that will yield But-2-ene upon dehydration with concentrated sulfuric acid is butan-2-ol. ### Final Answer: The correct answer is **Butan-2-ol**.

To determine which alcohol will yield But-2-ene upon dehydration with concentrated sulfuric acid (H₂SO₄), we need to analyze the structure of the alcohols provided in the options. ### Step-by-Step Solution: 1. **Understanding Dehydration Reaction**: Dehydration of alcohols involves the removal of a water molecule (H₂O) from the alcohol, leading to the formation of alkenes. The reaction typically requires an acid catalyst, such as concentrated sulfuric acid. 2. **Identify the Alcohols**: ...
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