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An alcohol X on heating with concentrate...

An alcohol X on heating with concentrated `H_(2)SO_(4)` gives an alkene Y which can show geometrical isomerism . The alcohol X is

A

`CH_(3)CH_(2)CH(OH)CH_(3)`

B

`(CH_(3))_(2)C(OH) CH(CH_(3))_(2)`

C

`(CH_(3))_(3) C(OH)`

D

`(CH_(3))_(2)C(OH) CH_(2)CH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify the alcohol (X) that, when heated with concentrated sulfuric acid (H₂SO₄), produces an alkene (Y) capable of exhibiting geometrical isomerism. ### Step-by-Step Solution: 1. **Understanding Geometrical Isomerism**: Geometrical isomerism occurs in compounds with restricted rotation around a double bond, typically alkenes. For an alkene to show geometrical isomerism, it must have two different groups attached to each carbon of the double bond. 2. **Identifying the Alcohol**: We need to consider the possible alcohols that can undergo dehydration (loss of water) when treated with concentrated H₂SO₄ to form an alkene. 3. **Analyzing the Options**: - **Option A**: CH₃CH₂CHOHCH₃ (2-butanol) - When heated with H₂SO₄, it can form CH₃CH=CHCH₃ (but-2-ene), which can show cis/trans isomerism. - **Option B**: CH₃C(CH₃)CHOH (2-pentanol) - This would also form an alkene but does not have the necessary structure to show geometrical isomerism. - **Option C**: CH₃C(CH₃)₂CHOH (2-methyl-2-propanol) - This would form an alkene that cannot show geometrical isomerism due to identical groups around the double bond. - **Option D**: CH₃CH₂CHOHCH₂CH₃ (1-pentanol) - This would form an alkene that cannot show geometrical isomerism either. 4. **Conclusion**: From the analysis, the only alcohol that can form an alkene capable of geometrical isomerism is **Option A: CH₃CH₂CHOHCH₃ (2-butanol)**. ### Final Answer: The alcohol X is **CH₃CH₂CHOHCH₃ (2-butanol)**.

To solve the question, we need to identify the alcohol (X) that, when heated with concentrated sulfuric acid (H₂SO₄), produces an alkene (Y) capable of exhibiting geometrical isomerism. ### Step-by-Step Solution: 1. **Understanding Geometrical Isomerism**: Geometrical isomerism occurs in compounds with restricted rotation around a double bond, typically alkenes. For an alkene to show geometrical isomerism, it must have two different groups attached to each carbon of the double bond. 2. **Identifying the Alcohol**: ...
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