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The best reagent to convert pent-3-en-2-...

The best reagent to convert pent-3-en-2-ol into pent-3-en-2-one is

A

acidic permanganate

B

acidic dichromate

C

chromic anhydride in glacial acetic acid

D

pyridinium chlorochromate.

Text Solution

AI Generated Solution

The correct Answer is:
To convert pent-3-en-2-ol into pent-3-en-2-one, we need to perform an oxidation reaction that specifically targets the alcohol functional group without affecting the alkene. Here’s a step-by-step solution: ### Step 1: Identify the structures - **Pent-3-en-2-ol**: This compound has a hydroxyl (-OH) group at the second carbon and a double bond between the third and fourth carbons. - **Pent-3-en-2-one**: This compound has a carbonyl (C=O) group at the second carbon and retains the double bond. ### Step 2: Determine the reaction type - We need to oxidize the alcohol (-OH) group to a ketone (C=O). This is an oxidation reaction. ### Step 3: Select the appropriate reagent - The reagent must selectively oxidize the alcohol to a ketone without affecting the alkene. - A suitable reagent for this transformation is **chromic anhydride (CrO3)** in **glacial acetic acid**. This reagent is known for its ability to oxidize alcohols to ketones. ### Step 4: Write the reaction - The reaction can be represented as follows: \[ \text{Pent-3-en-2-ol} + \text{CrO}_3 \text{ (in glacial acetic acid)} \rightarrow \text{Pent-3-en-2-one} \] ### Conclusion - Therefore, the best reagent to convert pent-3-en-2-ol into pent-3-en-2-one is **chromic anhydride in glacial acetic acid**.

To convert pent-3-en-2-ol into pent-3-en-2-one, we need to perform an oxidation reaction that specifically targets the alcohol functional group without affecting the alkene. Here’s a step-by-step solution: ### Step 1: Identify the structures - **Pent-3-en-2-ol**: This compound has a hydroxyl (-OH) group at the second carbon and a double bond between the third and fourth carbons. - **Pent-3-en-2-one**: This compound has a carbonyl (C=O) group at the second carbon and retains the double bond. ### Step 2: Determine the reaction type - We need to oxidize the alcohol (-OH) group to a ketone (C=O). This is an oxidation reaction. ...
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