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p-cresol reacts with chloroform in alkal...

p-cresol reacts with chloroform in alkaline medium to give the compound A which adds hydrogen cyanide to form, the compound B. the latter on acidic hydrolysis gives chiral caboxylic acid. The structure of the carboxylic acid is

A

B

C

D

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To solve the problem step-by-step, we will follow the reactions mentioned in the question involving p-cresol, chloroform, and hydrogen cyanide. ### Step 1: Identify the structure of p-cresol p-Cresol is a methylphenol with the following structure: - It has a hydroxyl group (-OH) and a methyl group (-CH3) attached to a benzene ring at the para position. **Structure of p-cresol:** ``` OH | CH3-C6H4 ``` ### Step 2: Reaction of p-cresol with chloroform in alkaline medium When p-cresol reacts with chloroform (CHCl3) in the presence of a strong base like KOH, it undergoes the Reimer-Tiemann reaction. This reaction converts phenols into ortho- and para-hydroxybenzaldehydes. **Product A:** In this case, the para position will be favored, leading to the formation of p-hydroxybenzaldehyde (also known as salicylaldehyde). **Structure of Product A:** ``` OH | CH3-C6H4-CHO ``` ### Step 3: Addition of hydrogen cyanide to Product A Next, we add hydrogen cyanide (HCN) to the aldehyde (Product A). The cyanide ion (CN-) will attack the carbonyl carbon of the aldehyde, leading to the formation of a cyanohydrin. **Product B:** The resulting compound will have both a hydroxyl group and a cyanide group. **Structure of Product B:** ``` OH | CH3-C6H4-CH(OH)-CN ``` ### Step 4: Acidic hydrolysis of Product B When Product B undergoes acidic hydrolysis, the cyanide group (-CN) is converted into a carboxylic acid (-COOH). This reaction also leads to the formation of a chiral center. **Final Product:** The final product after hydrolysis will be a chiral carboxylic acid. **Structure of the chiral carboxylic acid:** ``` OH | CH3-C6H4-COOH ``` ### Conclusion The structure of the chiral carboxylic acid formed is: ``` OH | CH3-C6H4-COOH ```

To solve the problem step-by-step, we will follow the reactions mentioned in the question involving p-cresol, chloroform, and hydrogen cyanide. ### Step 1: Identify the structure of p-cresol p-Cresol is a methylphenol with the following structure: - It has a hydroxyl group (-OH) and a methyl group (-CH3) attached to a benzene ring at the para position. **Structure of p-cresol:** ``` ...
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