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A primary alcohol, C(3)H(8)O(W) on heati...

A primary alcohol, `C_(3)H_(8)O(W)` on heating with sulphuric acid undergoes dehydration to give an alkene , (X), which reacts with HCl to give (Y). (Y) on treatment with aqueous KOH gives compound (Z),`C_(3)H_(8)O`. Compounds (W) and (Z) are `:`

A

functional isomers

B

position isomers

C

chain isomers

D

stereoisomers .

Text Solution

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The correct Answer is:
To solve the problem step by step, we will identify the compounds involved and their transformations. ### Step 1: Identify the Primary Alcohol (W) The primary alcohol with the formula \( C_3H_8O \) can be identified as **1-propanol** (CH3CH2CH2OH). ### Step 2: Dehydration Reaction When 1-propanol is heated with sulfuric acid (H2SO4), it undergoes dehydration (loss of water) to form an alkene. The reaction can be represented as follows: \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{OH} \xrightarrow{\text{H}_2\text{SO}_4, \text{heat}} \text{CH}_3\text{CH}=\text{CH}_2 + \text{H}_2\text{O} \] The product formed here is **propene** (CH3CH=CH2), which we will denote as (X). ### Step 3: Reaction with HCl The alkene (X), propene, reacts with hydrochloric acid (HCl) to form an alkyl halide. The reaction is as follows: \[ \text{CH}_3\text{CH}=\text{CH}_2 + \text{HCl} \rightarrow \text{CH}_3\text{CHClCH}_3 \] The product formed is **2-chloropropane** (CH3CHClCH3), which we will denote as (Y). ### Step 4: Reaction with Aqueous KOH The alkyl halide (Y), 2-chloropropane, reacts with aqueous potassium hydroxide (KOH) to undergo hydrolysis, yielding an alcohol. The reaction can be represented as: \[ \text{CH}_3\text{CHClCH}_3 + \text{KOH (aq)} \rightarrow \text{CH}_3\text{CHOHCH}_3 + \text{KCl} \] The product formed here is **2-propanol** (CH3CHOHCH3), which we will denote as (Z). ### Step 5: Identify Compounds W and Z - Compound (W) is **1-propanol** (C3H8O). - Compound (Z) is **2-propanol** (C3H8O). ### Final Answer The compounds (W) and (Z) are: - (W) = 1-Propanol (C3H8O) - (Z) = 2-Propanol (C3H8O)

To solve the problem step by step, we will identify the compounds involved and their transformations. ### Step 1: Identify the Primary Alcohol (W) The primary alcohol with the formula \( C_3H_8O \) can be identified as **1-propanol** (CH3CH2CH2OH). ### Step 2: Dehydration Reaction When 1-propanol is heated with sulfuric acid (H2SO4), it undergoes dehydration (loss of water) to form an alkene. The reaction can be represented as follows: ...
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