Home
Class 12
CHEMISTRY
Ethers are prepared by the reaction of s...

Ethers are prepared by the reaction of sodium alkoxides and alkyl halides. Which of the following reagents should be taken to prepare methyl tert-butyl ether ?

A

` (CH_3)_3 C- Br + NaOCH_3 `

B

`CH_3 Br + Na OC (CH_3)_3 `

C

` CH_3CH_2Br + NaOC (CH_3)_2 `

D

`(CH_3)_2 C- Br+NaOCH_2CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To prepare methyl tert-butyl ether, we need to follow the Williamson ether synthesis method, which involves the reaction of sodium alkoxide with an alkyl halide. Here’s a step-by-step solution to the question: ### Step-by-Step Solution: 1. **Identify the Required Ether**: We need to prepare methyl tert-butyl ether, which has the structure: \[ \text{(CH}_3\text{)}_3\text{C-O-CH}_3 \] This indicates that we need a tert-butyl group (from tert-butyl halide) and a methyl group (from methyl alkoxide). 2. **Determine the Alkoxide**: The alkoxide we require is sodium methoxide (NaOCH₃), which provides the methyl group. 3. **Determine the Alkyl Halide**: The alkyl halide needed is tert-butyl bromide (or tert-butyl chloride), which can be represented as: \[ \text{(CH}_3\text{)}_3\text{C-Br} \] This will provide the tert-butyl group. 4. **Reaction Setup**: The reaction will involve sodium methoxide (NaOCH₃) reacting with tert-butyl bromide ((CH₃)₃C-Br). The reaction can be summarized as: \[ \text{NaOCH}_3 + \text{(CH}_3\text{)}_3\text{C-Br} \rightarrow \text{(CH}_3\text{)}_3\text{C-O-CH}_3 + \text{NaBr} \] 5. **Mechanism**: The reaction proceeds via an SN2 mechanism, where the nucleophile (methoxide ion) attacks the electrophilic carbon in the tert-butyl halide, leading to the formation of the ether and the leaving group (Br⁻). 6. **Conclusion**: Therefore, the correct reagents to prepare methyl tert-butyl ether are sodium methoxide (NaOCH₃) and tert-butyl bromide ((CH₃)₃C-Br). ### Final Answer: The reagents needed to prepare methyl tert-butyl ether are **sodium methoxide (NaOCH₃)** and **tert-butyl bromide ((CH₃)₃C-Br)**. ---

To prepare methyl tert-butyl ether, we need to follow the Williamson ether synthesis method, which involves the reaction of sodium alkoxide with an alkyl halide. Here’s a step-by-step solution to the question: ### Step-by-Step Solution: 1. **Identify the Required Ether**: We need to prepare methyl tert-butyl ether, which has the structure: \[ \text{(CH}_3\text{)}_3\text{C-O-CH}_3 \] ...
Promotional Banner

Topper's Solved these Questions

  • ALCOHOLS,PHENOLS AND ETHERS

    NCERT FINGERTIPS ENGLISH|Exercise HOTS|7 Videos
  • ALCOHOLS,PHENOLS AND ETHERS

    NCERT FINGERTIPS ENGLISH|Exercise EXEMPLAR PROBLEMS|14 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos

Similar Questions

Explore conceptually related problems

Which of the following reaction can be used to prepare cyclic ethers ?

Which of the following compounds is oxidised to prepare methyl ethyl ketone?

Which of the following pairs of reagents will not form ether?

Which of the following reaction does not form an ether ?

Which of the following reagents can be used to prepare and alkyl halide from an alcohol (ROH) :-

Which among the following reagents convert alkyl halide into alkane ?

Which of the following reagents can be used to convert alkyl halide into alkane ?

Knowledge Check

  • Which of the following Grignard reagent can be prepared ?

    A
    `Br-Mg-CH_(2)-CH_(2)-CH_(2)-O-H`
    B
    `Br-Mg-CH_(2)-CH_(2)-SH`
    C
    `BrMg-CH_(2)-CH_(2)-NH_(2)`
    D
    `BrMg-CH_(2)-CH_(2)-underset(CH_(3))underset(|)(N)-CH_(3)`
  • Which of the following reactions would give the best yield of t-butyl methyl ether?

    A
    `(CH_(3))_(3)C-OHunderset(140^(@)C)overset(H_(2)SO_(4))to`
    B
    `(CH_(3))_(3)C-Br+CH_(3)OHto`
    C
    `(CH_(3))_(3)C-Br+CH_(3)overset(ө)(O)Na^(o+)to`
    D
    `(CH_(3))_(3)C-overset(ө)(O)overset(o+)(K)+CH_(3)Brto`
  • Which of the following reagents can be used to prepare an alkyl halide from an alcohol? Is

    A
    NaCl
    B
    `SOCl_(2)`
    C
    `PCl_(5)`
    D
    `HCl+ZnCl_(2)`