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Assertion (A) Addition reaction of water...

Assertion (A) Addition reaction of water to but-1-ene in acidic medium yields butan-1-ol.
Reason (R) Addition of water in acidic medium proceeds through the formation of primary carbocation.

A

if both assertioon and reason are true and reason is the corrct explanation of assertion.

B

If both assertion and reason are ture but reason is not the corrcet explanation of assertion.

C

If assertion is true but reason is false .

D

if both assertion and reason are false.

Text Solution

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The correct Answer is:
To solve the given question, we need to analyze both the assertion and the reason provided: ### Step 1: Understand the Assertion The assertion states that the addition reaction of water to but-1-ene in acidic medium yields butan-1-ol. - But-1-ene (C4H8) has the structure: \[ CH_2=CH-CH_2-CH_3 \] - When water is added to an alkene in the presence of an acid (H+), the reaction follows Markovnikov's rule, which states that the hydrogen atom from the acid will add to the carbon with more hydrogen atoms already attached, leading to the formation of a more stable carbocation. ### Step 2: Analyze the Reaction Mechanism In the case of but-1-ene: 1. The double bond between the first two carbon atoms can react with H+ from the acid. 2. According to Markovnikov's rule, H+ will add to the first carbon (C1), resulting in the formation of a secondary carbocation at C2: \[ CH_3-CH^+-CH_2-CH_3 \] 3. Water (H2O) will then attack this carbocation, leading to the formation of butan-2-ol (not butan-1-ol). ### Step 3: Conclusion on the Assertion Since the product formed is butan-2-ol, the assertion that the reaction yields butan-1-ol is **incorrect**. ### Step 4: Understand the Reason The reason states that the addition of water in acidic medium proceeds through the formation of a primary carbocation. - As established, the reaction actually proceeds through the formation of a **secondary carbocation**, which is more stable than a primary carbocation. - Therefore, the reason is also **incorrect**. ### Final Conclusion Both the assertion and the reason are incorrect. Thus, the correct answer to the question is that both the assertion and the reason are false. ### Summary of the Answer - **Assertion (A)**: Incorrect (yields butan-2-ol, not butan-1-ol). - **Reason (R)**: Incorrect (proceeds through secondary carbocation, not primary). - **Final Answer**: Both assertion and reason are false. ---

To solve the given question, we need to analyze both the assertion and the reason provided: ### Step 1: Understand the Assertion The assertion states that the addition reaction of water to but-1-ene in acidic medium yields butan-1-ol. - But-1-ene (C4H8) has the structure: \[ CH_2=CH-CH_2-CH_3 ...
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