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Which of the following alkenes is most r...

Which of the following alkenes is most reactive towards cationic polymerization?

A

a. `CH_(2)=CHCH_(3) `

B

b. `CH_(2)=CHCl `

C

c. `CH_(2)=CHC_(6)H_(5)`

D

d. `CH_(2)=CHCOOCH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
C

In cationic polymerisation , carbocations are formed. Greater the stability of the carbocation , more reactive is the alkene. Since the stability of the intermediate cabocation follows the order : `CH_(3)-overset(+)CH_(6)H_(5) gt CH_(3) overset(+)CH_(3 ) gt CH_(3)overset(+)(C)HCl gt CH_(3)overset(+)CHCOOCH_(3)` therefore , reactivity decreases in the same order. Thus, styrene is mots reactive.
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Knowledge Check

  • Which of the following alkenes is the most reactive towards cationic polymerisation ?

    A
    `CH_(2) = CHCH_(3)`
    B
    `H_(2)= CHCI`
    C
    `H_(2)C= CHC_(6)H_(5)`
    D
    `H_(2)C= CHCO_(2)CH_(3)`
  • Which of the following alkenes is least reactive towards anionic polymerisation ?

    A
    a. `CH_(2)=CHCH_(3) `
    B
    b. `CH_(2)=CF_(2)`
    C
    c. `CH_(2)=CHCN`
    D
    d. `CH_(2)=CHC_(6)H_(5)`
  • Which of the following haloalkanes is most reactive?

    A
    1-Chloropropane
    B
    1-bromopropane
    C
    2-chloropropane
    D
    2-bromopropane