Home
Class 11
CHEMISTRY
Few statements are given regarding nodes...

Few statements are given regarding nodes in the orbitals. Mark the statement which is not correct.

A

In case of `p_(z)`-orbital, xy plane is a nodal plane.

B

ns - orbital has (n + 1) nodes.

C

The number of angular nodes is given by l.

D

The total number of nodes is given by (n - 1) i.e. sum of l angular nodes and (n - l - 1) radial nodes.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement regarding nodes in orbitals is incorrect, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Understanding Nodes in Orbitals:** - Nodes are regions in an orbital where the probability of finding an electron is zero. There are two types of nodes: radial nodes and angular nodes. 2. **Analyzing the First Statement:** - **Statement:** "In case of Pz orbital, the xy plane is a nodal plane." - **Analysis:** The Pz orbital has nodal planes that are perpendicular to the z-axis, which includes the xy plane. Therefore, this statement is **correct**. 3. **Analyzing the Second Statement:** - **Statement:** "ns orbital has n + 1 nodes." - **Analysis:** The number of nodes in an ns orbital is calculated using the formula: \[ \text{Total Nodes} = n - 1 \] For an ns orbital, the number of nodes is \(n - 1\), not \(n + 1\). Thus, this statement is **incorrect**. 4. **Analyzing the Third Statement:** - **Statement:** "The number of angular nodes is given by L." - **Analysis:** The azimuthal quantum number \(L\) indeed represents the number of angular nodes. Therefore, this statement is **correct**. 5. **Analyzing the Fourth Statement:** - **Statement:** "The total number of nodes is given by n - 1, which is the sum of angular nodes and radial nodes." - **Analysis:** The total number of nodes is indeed \(n - 1\), which is the sum of angular nodes (L) and radial nodes (n - l - 1). Therefore, this statement is **correct**. ### Conclusion: After analyzing all statements, we find that the incorrect statement is: - **"ns orbital has n + 1 nodes."** ### Final Answer: The incorrect statement is: **"ns orbital has n + 1 nodes."** ---

To determine which statement regarding nodes in orbitals is incorrect, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Understanding Nodes in Orbitals:** - Nodes are regions in an orbital where the probability of finding an electron is zero. There are two types of nodes: radial nodes and angular nodes. 2. **Analyzing the First Statement:** ...
Promotional Banner

Topper's Solved these Questions

  • STRUCTURE OF ATOM

    NCERT FINGERTIPS ENGLISH|Exercise HIGHER ORDER THINKING SKILLS|11 Videos
  • STRUCTURE OF ATOM

    NCERT FINGERTIPS ENGLISH|Exercise NCERT EXEMPLAR PROBLEMS|16 Videos
  • STATES OF MATTER

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos
  • THE P-BLOCK ELEMENTS

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos

Similar Questions

Explore conceptually related problems

Give below are few statements. Mark the statement which is not correct.

Identify the statement which is not correct regarding CuSO_4 ?

Which statement regarding entropy is correct?

Which statements are correct regarding copper sulphate?

Which of the following statement regarding cillia is not correct ?

Which of the following statements regarding cilia is not correct

Statement-I : There are two spherical nodes in 3s-orbital. Because Statement-II : There is no angular node in 3s-orbital.

The correct statement regarding the third orbit of hydrgen atom is

Which of the following statements regarding hydrides is not correct ?

NCERT FINGERTIPS ENGLISH-STRUCTURE OF ATOM -Assertion And Reason
  1. Few statements are given regarding nodes in the orbitals. Mark the sta...

    Text Solution

    |

  2. Assertion : The characteristics of cathode rays do not depend upon the...

    Text Solution

    |

  3. Assertion : X-rays are used to study the interior of objects . Rea...

    Text Solution

    |

  4. Assertion : In Rutherford's alpha-particle scattering experiment, most...

    Text Solution

    |

  5. Assertion : All the isotopes of a given element show same chemical beh...

    Text Solution

    |

  6. Assertion : In electromagnetic spectrum, the small portion around 10^(...

    Text Solution

    |

  7. Assertion : When an iron rod is heated in a furnace, the radiation emi...

    Text Solution

    |

  8. Assertion : The number of electrons ejected from a metal surface depen...

    Text Solution

    |

  9. Assertion : Elements like Rb, Cs, Tl, In, Ga and Sc were discovered wh...

    Text Solution

    |

  10. Assertion : In hydrogen and hydrogen like species, orbital energy depe...

    Text Solution

    |

  11. Assertion : According to de Broglie, the wavelengths associated with e...

    Text Solution

    |

  12. Assertion : For l = 2, m(l) can be -2, -1, 0, +1 and +2. Reason : Fo...

    Text Solution

    |

  13. Assertion : Orbit and orbital are synonymous. Reason : A circular pa...

    Text Solution

    |

  14. Assertion : 3d(z^(2)) orbital is spherically symmetrical. Reason : T...

    Text Solution

    |

  15. Assertion : The maximum number of electrons in the shell with principl...

    Text Solution

    |

  16. Assertion : The outer electronic configuration of Cr and Cu are 3d^...

    Text Solution

    |