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Assertion : 3d(z^(2)) orbital is spheric...

Assertion : `3d_(z^(2))` orbital is spherically symmetrical.
Reason : The shapes of all five d-orbitals are similar to each other.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given assertion and reason, we will break down each statement step by step. ### Step 1: Understand the Assertion The assertion states that the `3d_(z^2)` orbital is spherically symmetrical. **Analysis**: - The `3d_(z^2)` orbital, also known as the d-z squared orbital, has a distinct shape that is not spherical. It has a "doughnut" shape around the z-axis and a lobe extending along the z-axis. Therefore, this assertion is **false**. ### Step 2: Understand the Reason The reason states that the shapes of all five d-orbitals are similar to each other. **Analysis**: - The five d-orbitals are: 1. `d_(xy)` 2. `d_(yz)` 3. `d_(zx)` 4. `d_(x^2 - y^2)` 5. `d_(z^2)` - Each of these orbitals has a unique shape. For example, the `d_(xy)`, `d_(yz)`, and `d_(zx)` orbitals have a cloverleaf shape, while the `d_(z^2)` orbital has a different shape with a lobe along the z-axis and a torus around the equator. Therefore, the reason is also **false**. ### Step 3: Conclusion Since both the assertion and the reason are false, the correct answer to the question is that both statements are incorrect. ### Final Answer Both the assertion and the reason are false. ---
To analyze the given assertion and reason, we will break down each statement step by step. ### Step 1: Understand the Assertion The assertion states that the `3d_(z^2)` orbital is spherically symmetrical. **Analysis**: - The `3d_(z^2)` orbital, also known as the d-z squared orbital, has a distinct shape that is not spherical. It has a "doughnut" shape around the z-axis and a lobe extending along the z-axis. Therefore, this assertion is **false**. ...
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