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Match the bond enthalpies given in colum...

Match the bond enthalpies given in column II with the molecules given in column I and mark the appropriate choice.
`{:(,"Column I",,"Column II "),((A),"Hydrogen "(H_(2)),(i),498.0 " kJ mol"^(-1)),((B),"Oxygen"(O_(2)),(ii),946.0" kJ mol"^(-1)),((C),"Nitrogen"(N_(2)),(iii),435.8 " kJ mol"^(-1)):}`

A

`(A)to(i), (B)to(ii), (C) to (iii)`

B

`(A) to (iii), (B) to (ii), (C ) to (i) `

C

`(A) to (i), (B) to (iii), (C ) to (ii)`

D

`(A) to (iii), (B) to (i), (C ) to (ii)`

Text Solution

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The correct Answer is:
To solve the problem of matching the bond enthalpies with the corresponding molecules, we can follow these steps: ### Step 1: Understand Bond Enthalpy Bond enthalpy (or bond energy) is defined as the amount of energy required to break one mole of a specific type of bond in a molecule. The stronger the bond, the higher the bond enthalpy. ### Step 2: Analyze the Molecules in Column I - **A: Hydrogen (H₂)** - Contains a single bond between two hydrogen atoms. - **B: Oxygen (O₂)** - Contains a double bond between two oxygen atoms. - **C: Nitrogen (N₂)** - Contains a triple bond between two nitrogen atoms. ### Step 3: Analyze the Bond Enthalpies in Column II - **i: 498.0 kJ mol⁻¹** - **ii: 946.0 kJ mol⁻¹** - **iii: 435.8 kJ mol⁻¹** ### Step 4: Compare the Strength of Bonds - Single bonds (like in H₂) are the weakest. - Double bonds (like in O₂) are stronger than single bonds but weaker than triple bonds. - Triple bonds (like in N₂) are the strongest. ### Step 5: Match the Bond Enthalpies 1. **Hydrogen (H₂)** has the weakest bond (single bond), so it will correspond to the lowest bond enthalpy. Thus, it matches with **(iii) 435.8 kJ mol⁻¹**. 2. **Oxygen (O₂)** has a double bond, which is stronger than a single bond but weaker than a triple bond. It matches with **(i) 498.0 kJ mol⁻¹**. 3. **Nitrogen (N₂)** has the strongest bond (triple bond), so it corresponds to the highest bond enthalpy. Thus, it matches with **(ii) 946.0 kJ mol⁻¹**. ### Final Matches - A (H₂) - iii (435.8 kJ mol⁻¹) - B (O₂) - i (498.0 kJ mol⁻¹) - C (N₂) - ii (946.0 kJ mol⁻¹) ### Conclusion The correct matching is: - A → iii - B → i - C → ii

To solve the problem of matching the bond enthalpies with the corresponding molecules, we can follow these steps: ### Step 1: Understand Bond Enthalpy Bond enthalpy (or bond energy) is defined as the amount of energy required to break one mole of a specific type of bond in a molecule. The stronger the bond, the higher the bond enthalpy. ### Step 2: Analyze the Molecules in Column I - **A: Hydrogen (H₂)** - Contains a single bond between two hydrogen atoms. - **B: Oxygen (O₂)** - Contains a double bond between two oxygen atoms. ...
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