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Arrange the following in decreasing orde...

Arrange the following in decreasing order of dipole moment <

A

`BF_(3) lt H_(2)S lt H_(2)O`

B

`H_(2)S lt BF_(3)ltH_(2)O`

C

`H_(2)O lt H_(2)S lt BF_(3)`

D

`BF_(3) lt H_(2)O lt H_(2)S`

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The correct Answer is:
To arrange the compounds BF3, H2S, and H2O in decreasing order of dipole moment, we will follow these steps: ### Step 1: Analyze the structure of BF3 - **Structure**: BF3 has a trigonal planar geometry due to sp2 hybridization of boron. It has three fluorine atoms symmetrically arranged around the boron atom. - **Dipole Moment**: The individual bond dipoles (B-F) cancel each other out due to symmetry, resulting in a net dipole moment of zero. **Conclusion**: Dipole moment of BF3 = 0. ### Step 2: Analyze the structure of H2S - **Structure**: H2S has a bent shape due to the presence of two lone pairs on the sulfur atom, which leads to sp3 hybridization. - **Dipole Moment**: The bond dipoles (H-S) do not cancel out completely because of the bent shape, resulting in a net dipole moment. **Conclusion**: Dipole moment of H2S > 0. ### Step 3: Analyze the structure of H2O - **Structure**: H2O also has a bent shape due to two lone pairs on the oxygen atom, leading to sp3 hybridization. - **Dipole Moment**: The bond dipoles (H-O) are directed towards the oxygen atom, and since oxygen is more electronegative than sulfur, the dipole moment is stronger than that of H2S. **Conclusion**: Dipole moment of H2O > Dipole moment of H2S. ### Step 4: Compare the dipole moments - We have established that: - Dipole moment of BF3 = 0 - Dipole moment of H2S > 0 - Dipole moment of H2O > Dipole moment of H2S ### Final Arrangement Thus, the decreasing order of dipole moments is: **H2O > H2S > BF3**

To arrange the compounds BF3, H2S, and H2O in decreasing order of dipole moment, we will follow these steps: ### Step 1: Analyze the structure of BF3 - **Structure**: BF3 has a trigonal planar geometry due to sp2 hybridization of boron. It has three fluorine atoms symmetrically arranged around the boron atom. - **Dipole Moment**: The individual bond dipoles (B-F) cancel each other out due to symmetry, resulting in a net dipole moment of zero. **Conclusion**: Dipole moment of BF3 = 0. ...
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NCERT FINGERTIPS ENGLISH-CHEMICAL BONDING & MOLECULAR STRUCTURE-Assertion And Reason
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  5. Assertion : PF(5),SF(6)and H(2)SO(4) are the examples of expanded octe...

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  6. Assertion : Octet rule is based upon the chemical inertness of noble g...

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  7. Assertion : Sodium chloride (NaCl) is a stable ionic solid. Reason ...

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  8. Assertion : F(2)and O(2)^(2-)have bond order 1 while N(2),CO and NO^(+...

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  9. Assertion : The experimentally determined carbon to oxygen bond length...

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  10. Assertion : The dipole moment in case of BeF(2) is zero. Reason : T...

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  11. Assertion : Dipole moment of NH(3) is greater than that of NF(3). Re...

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  12. Assertion : Among alkaline earth metals, Be predominantly forms covale...

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  13. Assertion : In NH(3), N "is " sp^(3) hybridised but bond angle is 107^...

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  14. Ionic bonds are non-directional while covalent bonds are directional.

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  15. Assertion : O(2) molecule is diamagnetic while C(2) molecule is parama...

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  16. Assertion : Boiling point of p-nitrophenol is greater than that of o-n...

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