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CF(4), SF(4) and XeF(4) contain the foll...

`CF_(4), SF_(4) and XeF_(4)` contain the following electronic structure on their central atoms. Which one is correct option ?

A

1, 2 and 3 lone pairs of electrons respectively

B

0,1 and 2 lone pairs of electrons respectively

C

1,1 and 1 lone pairs of electrons respectively

D

No lone pairs of electrons on anly molecule

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The correct Answer is:
To determine the number of lone pairs in the molecules CF₄, SF₄, and XeF₄, we need to analyze the electronic structure of the central atoms in each molecule. Let's go through each molecule step by step. ### Step 1: Analyze CF₄ (Carbon Tetrafluoride) 1. **Identify the central atom**: The central atom in CF₄ is Carbon (C). 2. **Determine the number of valence electrons**: Carbon has 4 valence electrons (group 14). 3. **Count the bonds formed**: In CF₄, Carbon forms 4 bonds with 4 Fluorine (F) atoms. 4. **Calculate lone pairs**: Since all 4 valence electrons are used to form bonds, there are no electrons left for lone pairs. - **Lone pairs in CF₄**: 0 ### Step 2: Analyze SF₄ (Sulfur Tetrafluoride) 1. **Identify the central atom**: The central atom in SF₄ is Sulfur (S). 2. **Determine the number of valence electrons**: Sulfur has 6 valence electrons (group 16). 3. **Count the bonds formed**: In SF₄, Sulfur forms 4 bonds with 4 Fluorine atoms. 4. **Calculate lone pairs**: Sulfur uses 4 of its 6 valence electrons to form bonds, leaving 2 electrons. - These 2 remaining electrons form 1 lone pair. - **Lone pairs in SF₄**: 1 ### Step 3: Analyze XeF₄ (Xenon Tetrafluoride) 1. **Identify the central atom**: The central atom in XeF₄ is Xenon (Xe). 2. **Determine the number of valence electrons**: Xenon has 8 valence electrons (group 18). 3. **Count the bonds formed**: In XeF₄, Xenon forms 4 bonds with 4 Fluorine atoms. 4. **Calculate lone pairs**: Xenon uses 4 of its 8 valence electrons to form bonds, leaving 4 electrons. - These 4 remaining electrons can form 2 lone pairs. - **Lone pairs in XeF₄**: 2 ### Final Summary - CF₄ has **0 lone pairs**. - SF₄ has **1 lone pair**. - XeF₄ has **2 lone pairs**. Thus, the correct option is **B: 0, 1, and 2 lone pairs of electrons respectively**. ---

To determine the number of lone pairs in the molecules CF₄, SF₄, and XeF₄, we need to analyze the electronic structure of the central atoms in each molecule. Let's go through each molecule step by step. ### Step 1: Analyze CF₄ (Carbon Tetrafluoride) 1. **Identify the central atom**: The central atom in CF₄ is Carbon (C). 2. **Determine the number of valence electrons**: Carbon has 4 valence electrons (group 14). 3. **Count the bonds formed**: In CF₄, Carbon forms 4 bonds with 4 Fluorine (F) atoms. 4. **Calculate lone pairs**: Since all 4 valence electrons are used to form bonds, there are no electrons left for lone pairs. - **Lone pairs in CF₄**: 0 ...
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NCERT FINGERTIPS ENGLISH-CHEMICAL BONDING & MOLECULAR STRUCTURE-Assertion And Reason
  1. CF(4), SF(4) and XeF(4) contain the following electronic structure on ...

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  2. Assertion : In the formation of a molecule , only the outer shell ele...

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  3. Assertion : In the formation of water molecule, both hydrogen and oxyg...

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  4. Assertion : In Liwis structures of NF(3) and CO(3)^(2-), nitrogen and...

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  5. Assertion : PF(5),SF(6)and H(2)SO(4) are the examples of expanded octe...

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  6. Assertion : Octet rule is based upon the chemical inertness of noble g...

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  7. Assertion : Sodium chloride (NaCl) is a stable ionic solid. Reason ...

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  8. Assertion : F(2)and O(2)^(2-)have bond order 1 while N(2),CO and NO^(+...

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  9. Assertion : The experimentally determined carbon to oxygen bond length...

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  10. Assertion : The dipole moment in case of BeF(2) is zero. Reason : T...

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  11. Assertion : Dipole moment of NH(3) is greater than that of NF(3). Re...

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  12. Assertion : Among alkaline earth metals, Be predominantly forms covale...

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  13. Assertion : In NH(3), N "is " sp^(3) hybridised but bond angle is 107^...

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  14. Ionic bonds are non-directional while covalent bonds are directional.

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  15. Assertion : O(2) molecule is diamagnetic while C(2) molecule is parama...

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  16. Assertion : Boiling point of p-nitrophenol is greater than that of o-n...

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