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Which one shows maximum hydrogen bonding...

Which one shows maximum hydrogen bonding ?

A

HF

B

`H_(2)O`

C

`NH_(3)`

D

`CH_(3)OH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound shows maximum hydrogen bonding among HF, H2O, NH3, and CH3OH, we can follow these steps: ### Step 1: Understand Hydrogen Bonding Hydrogen bonding occurs when a hydrogen atom covalently bonded to a highly electronegative atom (like F, O, or N) is attracted to another electronegative atom. The strength of hydrogen bonding is influenced by the electronegativity of the atom to which hydrogen is bonded and the size of that atom. ### Step 2: Identify the Atoms in Each Compound - **HF**: Hydrogen is bonded to fluorine (F). - **H2O**: Hydrogen is bonded to oxygen (O). - **NH3**: Hydrogen is bonded to nitrogen (N). - **CH3OH**: Hydrogen is bonded to oxygen (O) in the hydroxyl group (-OH). ### Step 3: Compare Electronegativity Next, we compare the electronegativities of the atoms involved: - **Fluorine (F)**: Highest electronegativity (around 4.0) - **Oxygen (O)**: Second highest (around 3.5) - **Nitrogen (N)**: Lower than oxygen (around 3.0) - **Carbon (C)**: Lowest among these (around 2.5) ### Step 4: Analyze the Results Since hydrogen bonding is directly proportional to the electronegativity of the atom bonded to hydrogen, we can conclude: - HF has the highest electronegativity (F), thus it will have the strongest hydrogen bonding. - H2O has a high electronegativity (O), but lower than HF. - NH3 has nitrogen, which has lower electronegativity than both F and O. - CH3OH has oxygen, similar to H2O, but the presence of carbon reduces its overall hydrogen bonding capability compared to HF. ### Step 5: Conclusion Based on the analysis, HF (hydrogen fluoride) shows the maximum hydrogen bonding due to the presence of fluorine, the most electronegative element. ### Final Answer The compound that shows maximum hydrogen bonding is **HF (hydrogen fluoride)**.

To determine which compound shows maximum hydrogen bonding among HF, H2O, NH3, and CH3OH, we can follow these steps: ### Step 1: Understand Hydrogen Bonding Hydrogen bonding occurs when a hydrogen atom covalently bonded to a highly electronegative atom (like F, O, or N) is attracted to another electronegative atom. The strength of hydrogen bonding is influenced by the electronegativity of the atom to which hydrogen is bonded and the size of that atom. ### Step 2: Identify the Atoms in Each Compound - **HF**: Hydrogen is bonded to fluorine (F). - **H2O**: Hydrogen is bonded to oxygen (O). ...
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NCERT FINGERTIPS ENGLISH-CHEMICAL BONDING & MOLECULAR STRUCTURE-Assertion And Reason
  1. Which one shows maximum hydrogen bonding ?

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  2. Assertion : In the formation of a molecule , only the outer shell ele...

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  3. Assertion : In the formation of water molecule, both hydrogen and oxyg...

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  4. Assertion : In Liwis structures of NF(3) and CO(3)^(2-), nitrogen and...

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  5. Assertion : PF(5),SF(6)and H(2)SO(4) are the examples of expanded octe...

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  6. Assertion : Octet rule is based upon the chemical inertness of noble g...

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  7. Assertion : Sodium chloride (NaCl) is a stable ionic solid. Reason ...

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  8. Assertion : F(2)and O(2)^(2-)have bond order 1 while N(2),CO and NO^(+...

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  9. Assertion : The experimentally determined carbon to oxygen bond length...

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  10. Assertion : The dipole moment in case of BeF(2) is zero. Reason : T...

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  11. Assertion : Dipole moment of NH(3) is greater than that of NF(3). Re...

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  12. Assertion : Among alkaline earth metals, Be predominantly forms covale...

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  13. Assertion : In NH(3), N "is " sp^(3) hybridised but bond angle is 107^...

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  14. Ionic bonds are non-directional while covalent bonds are directional.

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  15. Assertion : O(2) molecule is diamagnetic while C(2) molecule is parama...

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  16. Assertion : Boiling point of p-nitrophenol is greater than that of o-n...

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