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Though covalent in nature, methanol is ...

Though covalent in nature, methanol is soluble in water , why ?

A

Methanol is transparent like water.

B

Due to hydrogen bonding between methanol and water molecules.

C

Due to van der Waals' forces between methanol and water.

D

Due to covalent attraction forces.

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The correct Answer is:
**Step-by-Step Solution:** 1. **Understanding the Nature of Methanol:** - Methanol (CH₃OH) is a covalent compound. It consists of carbon, hydrogen, and oxygen atoms bonded together. 2. **Identifying the Structure of Methanol:** - The molecular structure of methanol can be represented as: \[ \text{H}_3\text{C-OH} \] - In this structure, the oxygen atom is more electronegative than hydrogen, which leads to a polar covalent bond between oxygen and hydrogen. 3. **Polarity of Methanol:** - Due to the difference in electronegativity, the oxygen atom carries a partial negative charge (δ-) and the hydrogen atom carries a partial positive charge (δ+). This makes methanol a polar molecule. 4. **Understanding Water's Structure:** - Water (H₂O) is also a polar molecule, where the oxygen atom is bonded to two hydrogen atoms. The oxygen atom in water also carries a partial negative charge, while the hydrogen atoms carry partial positive charges. 5. **Hydrogen Bonding:** - The partial positive charge of the hydrogen atoms in methanol can interact with the partial negative charge of the oxygen in water, and vice versa. This interaction is known as hydrogen bonding. - The hydrogen bonds formed between methanol and water molecules are significant because they are relatively strong intermolecular forces. 6. **Solubility of Methanol in Water:** - The hydrogen bonding between methanol and water molecules allows methanol to dissolve in water. The strong attraction between the polar molecules overcomes the forces holding the methanol molecules together, leading to its solubility. 7. **Conclusion:** - Therefore, the reason methanol is soluble in water, despite being covalent in nature, is due to the hydrogen bonding between methanol and water molecules. **Final Answer:** Methanol is soluble in water due to hydrogen bonding between methanol and water molecules. ---

**Step-by-Step Solution:** 1. **Understanding the Nature of Methanol:** - Methanol (CH₃OH) is a covalent compound. It consists of carbon, hydrogen, and oxygen atoms bonded together. 2. **Identifying the Structure of Methanol:** - The molecular structure of methanol can be represented as: \[ ...
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NCERT FINGERTIPS ENGLISH-CHEMICAL BONDING & MOLECULAR STRUCTURE-Assertion And Reason
  1. Though covalent in nature, methanol is soluble in water , why ?

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  2. Assertion : In the formation of a molecule , only the outer shell ele...

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  3. Assertion : In the formation of water molecule, both hydrogen and oxyg...

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  4. Assertion : In Liwis structures of NF(3) and CO(3)^(2-), nitrogen and...

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  5. Assertion : PF(5),SF(6)and H(2)SO(4) are the examples of expanded octe...

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  6. Assertion : Octet rule is based upon the chemical inertness of noble g...

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  7. Assertion : Sodium chloride (NaCl) is a stable ionic solid. Reason ...

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  8. Assertion : F(2)and O(2)^(2-)have bond order 1 while N(2),CO and NO^(+...

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  9. Assertion : The experimentally determined carbon to oxygen bond length...

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  10. Assertion : The dipole moment in case of BeF(2) is zero. Reason : T...

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  11. Assertion : Dipole moment of NH(3) is greater than that of NF(3). Re...

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  12. Assertion : Among alkaline earth metals, Be predominantly forms covale...

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  13. Assertion : In NH(3), N "is " sp^(3) hybridised but bond angle is 107^...

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  14. Ionic bonds are non-directional while covalent bonds are directional.

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  15. Assertion : O(2) molecule is diamagnetic while C(2) molecule is parama...

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  16. Assertion : Boiling point of p-nitrophenol is greater than that of o-n...

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