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The dipole moment of LiH is 1.964 xx10^(...

The dipole moment of `LiH` is `1.964 xx10^(-29)Cm` and the interatomic distance between `Li` and `H` in this molecule is `1.596Å` .What is the per cent ionic character in `LiH`.

A

`75.0`

B

`76.8`

C

`79.8`

D

100

Text Solution

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The correct Answer is:
To find the percentage ionic character in lithium hydride (LiH), we can follow these steps: ### Step 1: Identify the given values - **Dipole moment (μ)**: \(1.964 \times 10^{-29} \, \text{Cm}\) - **Interatomic distance (d)**: \(1.596 \, \text{Å} = 1.596 \times 10^{-10} \, \text{m} = 1.596 \times 10^{-8} \, \text{cm}\) ### Step 2: Calculate the theoretical dipole moment (μ theoretical) The theoretical dipole moment can be calculated using the formula: \[ \mu_{\text{theoretical}} = q \times d \] where: - \(q\) is the charge of an electron, approximately \(1.602 \times 10^{-19} \, \text{C}\) - \(d\) is the interatomic distance in centimeters. Substituting the values: \[ \mu_{\text{theoretical}} = (1.602 \times 10^{-19} \, \text{C}) \times (1.596 \times 10^{-8} \, \text{cm}) \] Calculating this gives: \[ \mu_{\text{theoretical}} = 2.557 \times 10^{-29} \, \text{Cm} \] ### Step 3: Calculate the percentage ionic character The percentage ionic character can be calculated using the formula: \[ \text{Percentage ionic character} = \left( \frac{\mu_{\text{experimental}}}{\mu_{\text{theoretical}}} \right) \times 100 \] Substituting the values: \[ \text{Percentage ionic character} = \left( \frac{1.964 \times 10^{-29}}{2.557 \times 10^{-29}} \right) \times 100 \] Calculating this gives: \[ \text{Percentage ionic character} \approx 76.8\% \] ### Final Answer The percentage ionic character in LiH is approximately **76.8%**. ---

To find the percentage ionic character in lithium hydride (LiH), we can follow these steps: ### Step 1: Identify the given values - **Dipole moment (μ)**: \(1.964 \times 10^{-29} \, \text{Cm}\) - **Interatomic distance (d)**: \(1.596 \, \text{Å} = 1.596 \times 10^{-10} \, \text{m} = 1.596 \times 10^{-8} \, \text{cm}\) ### Step 2: Calculate the theoretical dipole moment (μ theoretical) The theoretical dipole moment can be calculated using the formula: ...
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