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Value of gas constant R in the ideal gas...

Value of gas constant R in the ideal gas equation PV = nRT depends upon

A

temperature of the gas

B

pressure of the gas

C

units in which P , V and T are measured

D

nature of the gas .

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To determine what the value of the gas constant \( R \) in the ideal gas equation \( PV = nRT \) depends upon, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Ideal Gas Equation**: The ideal gas equation is given by \( PV = nRT \), where: - \( P \) = pressure of the gas - \( V \) = volume of the gas - \( n \) = number of moles of the gas - \( R \) = universal gas constant - \( T \) = temperature of the gas (in Kelvin) 2. **Rearranging the Equation**: We can rearrange the equation to express \( R \): \[ R = \frac{PV}{nT} \] This shows that \( R \) is derived from the values of \( P \), \( V \), \( n \), and \( T \). 3. **Identifying Dependencies**: From the equation \( R = \frac{PV}{nT} \), we can see that: - The value of \( R \) depends on the values of \( P \), \( V \), and \( T \). - The units in which \( P \), \( V \), and \( T \) are measured will affect the calculated value of \( R \). 4. **Considering Different Conditions**: The value of \( R \) can change based on the conditions under which the gas is measured. For example: - At Standard Temperature and Pressure (STP), the value of \( R \) is typically \( 0.0821 \, \text{L atm K}^{-1} \text{mol}^{-1} \). - At different conditions (like Normal Temperature and Pressure, NTP), the value may differ. 5. **Conclusion**: Therefore, the value of the gas constant \( R \) depends on: - The temperature of the gas - The pressure of the gas - The units in which \( P \), \( V \), and \( T \) are measured ### Final Answer: The value of the gas constant \( R \) in the ideal gas equation \( PV = nRT \) depends upon the units in which \( P \), \( V \), and \( T \) are measured.
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Out of the three states of matter, only the gases have most of the physical properties common. They neither have definite shapes nor volumes. Upon mixing they form homogeneous mixture irrespective of their nature and can also be compressed on applying pressure. In addition to these, the gases obey different gas laws such as Boyle's Law, Charles's Law, Dalton's Law of partial pressures, Graham's Law of diffusion etc. Based upon these laws, ideal gas equation PV = nRT has been derived. For an ideal gas, number of moles per litre in terms of its pressure P, gas constant R and temperature T is :

van der Waal's equation for calculating the pressure of a non ideal gas is (P+(an^(2))/(V^(2)))(V-nb)=nRT van der Waal's suggested that the pressure exerted by an ideal gas , P_("ideal") , is related to the experiventally measured pressure, P_("ideal") by the equation P_("ideal")=underset("observed pressure")(underset(uarr)(P_("real")))+underset("currection term")(underset(uarr)((an^(2))/(V^(2)))) Constant 'a' is measure of intermolecular interaction between gaseous molecules that gives rise to nonideal behavior. It depends upon how frequently any two molecules approach each other closely. Another correction concerns the volume occupied by the gas molecules. In the ideal gas equation, V represents the volume of the container. However, each molecule does occupy a finite, although small, intrinsic volume, so the effective volume of the gas vecomes (V-nb), where n is the number of moles of the gas and b is a constant. The term nb represents the volume occupied by gas particles present in n moles of the gas . Having taken into account the corrections for pressure and volume, we can rewrite the ideal gas equation as follows : underset("corrected pressure")((P+(an^(2))/(V^(2))))underset("corrected volume")((V-nb))=nRT AT relatively high pressures, the van der Waals' equation of state reduces to

Out of three states of matter, only the gases have most of the physical properties common. They have neither definite shapes nor definite volume. In addition to this, the gases obey different gas laws such as Boyles's law. Charles law, Dalton's law of partial pressures etc. Based upon these gas laws, ideal gas equation PV = nRT has been derived. Answer the following questions on the basis of above paragraph. (i) what is Dalton's law of partial pressures ? (ii) Derive ideal gas equation on the basis of all gas laws.

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