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Under what conditions to gases show maxi...

Under what conditions to gases show maximum deviations from ideal gas behaviour ?

A

At high temperature and low pressure

B

At low temperature and high pressure

C

At high temperature and high pressure

D

At low temperature and low pressure

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The correct Answer is:
### Step-by-Step Solution: 1. **Understanding Ideal Gas Behavior**: - Ideal gases follow the ideal gas law, which states that PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature. - Ideal gas behavior assumes that gas particles have no volume and do not exert forces on each other. 2. **Conditions for Ideal Gas Behavior**: - Gases behave ideally at high temperatures and low pressures. - At high temperatures, the kinetic energy of gas molecules is high, which minimizes intermolecular forces. - At low pressures, gas molecules are far apart, reducing the effects of volume and intermolecular forces. 3. **Conditions Leading to Deviations**: - Deviations from ideal gas behavior occur when the assumptions of the ideal gas law are no longer valid. - This typically happens at low temperatures and high pressures. 4. **Low Temperature**: - At low temperatures, gas molecules have lower kinetic energy, leading to increased intermolecular attractions. - These attractions cause the gas to behave less ideally, as the volume of the gas particles and the forces between them become significant. 5. **High Pressure**: - At high pressures, gas molecules are forced closer together, which makes their volume significant compared to the total volume of the gas. - The increased density also enhances intermolecular forces, leading to further deviations from ideal behavior. 6. **Conclusion**: - Therefore, gases show maximum deviations from ideal gas behavior at low temperatures and high pressures. ### Final Answer: Gases show maximum deviations from ideal gas behavior at **low temperature and high pressure**. ---

### Step-by-Step Solution: 1. **Understanding Ideal Gas Behavior**: - Ideal gases follow the ideal gas law, which states that PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature. - Ideal gas behavior assumes that gas particles have no volume and do not exert forces on each other. 2. **Conditions for Ideal Gas Behavior**: - Gases behave ideally at high temperatures and low pressures. ...
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The gases obey the different gas laws only theoretically. Practically all of them show some deviation from these laws. These are called real gases. The deviation are maximum under high pressure and at low temperature. These are comparatively small when the conditions are reversed. It has been found that the easily liquefiable gases show more deviations from the ideal gas behaviour as compared to the gases which are liquified with difficulty. Gas deviates from ideal gas behaviour because molecules

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The gases obey the different gas laws only theoretically. Practically all of them show some deviation from these laws. These are called real gases. The deviation are maximum under high pressure and at low temperature. These are comparatively small when the conditions are reversed. It has been found that the easily liquefiable gases show more deviations from the ideal gas behaviour as compared to the gases which are liquified with difficulty. The temperature at which the real gases obey the ideal gas laws over a wide range of pressure is called

The gases obey the different gas laws only theoretically. Practically all of them show some deviation from these laws. These are called real gases. The deviation are maximum under high pressure and at low temperature. These are comparatively small when the conditions are reversed. It has been found that the easily liquefiable gases show more deviations from the ideal gas behaviour as compared to the gases which are liquified with difficulty. The van der Waals equation reduces itself to ideal gas equation at

The gases obey the different gas laws only theoretically. Practically all of them show some deviation from these laws. These are called real gases. The deviation are maximum under high pressure and at low temperature. These are comparatively small when the conditions are reversed. It has been found that the easily liquefiable gases show more deviations from the ideal gas behaviour as compared to the gases which are liquified with difficulty. The compressibility factor for an ideal gas is :

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