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Enthalpy change for the process, H(2)O...

Enthalpy change for the process,
`H_(2)O"(ice")hArr H_(2)O"(water)"`
is `"6.01 kJ mol"^(-1)`. The entropy change of 1 mole of ice at its melting point will be

A

`"12 J K"^(-1)"mol"^(-1)`

B

`"22 J K"^(-1)"mol"^(-1)`

C

`"100 J K"^(-1)"mol"^(-1)`

D

`"30 J K"^(-1)"mol"^(-1)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the entropy change (ΔS) for the process of melting ice (H₂O solid) to water (H₂O liquid), we can use the formula: \[ \Delta S = \frac{\Delta H}{T} \] where: - ΔH is the enthalpy change, - T is the temperature in Kelvin. ### Step 1: Identify the given values - The enthalpy change (ΔH) for the melting of ice is given as 6.01 kJ/mol. - The melting point of ice is 0°C. ### Step 2: Convert the enthalpy change from kJ to J Since we need to express ΔH in joules for our calculations, we convert it: \[ \Delta H = 6.01 \, \text{kJ/mol} = 6.01 \times 1000 \, \text{J/mol} = 6010 \, \text{J/mol} \] ### Step 3: Convert the temperature from Celsius to Kelvin The melting point of ice is 0°C. To convert this to Kelvin: \[ T = 0°C + 273.15 = 273.15 \, \text{K} \approx 273 \, \text{K} \] ### Step 4: Substitute the values into the entropy change formula Now we can substitute the values of ΔH and T into the entropy change formula: \[ \Delta S = \frac{6010 \, \text{J/mol}}{273 \, \text{K}} \] ### Step 5: Calculate the entropy change Now we perform the calculation: \[ \Delta S \approx \frac{6010}{273} \approx 22.0 \, \text{J/K/mol} \] ### Final Answer The entropy change (ΔS) for the melting of 1 mole of ice at its melting point is approximately: \[ \Delta S \approx 22.0 \, \text{J/K/mol} \] ---

To find the entropy change (ΔS) for the process of melting ice (H₂O solid) to water (H₂O liquid), we can use the formula: \[ \Delta S = \frac{\Delta H}{T} \] where: - ΔH is the enthalpy change, ...
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