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Which of the following statements regard...

Which of the following statements regarding Gibb's energy change is correct?

A

If `DeltaG` is negative (lt 0), the process is non-spontaneous.

B

If `DeltaG` is positive ( gt 0), the processis spontaneous.

C

If `DeltaG` is negative ( lt 0), the process is spontaneous.

D

If `DeltaG` is positive (gt 0), the process is in equilibrium.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement regarding Gibbs energy change is correct, we will analyze the Gibbs free energy equation and the implications of its values. ### Step 1: Understand the Gibbs Free Energy Equation The Gibbs free energy change (ΔG) is given by the equation: \[ \Delta G = \Delta H - T \Delta S \] where: - ΔG = change in Gibbs free energy - ΔH = change in enthalpy - T = temperature in Kelvin - ΔS = change in entropy ### Step 2: Analyze the Conditions for Spontaneity - A process is **spontaneous** if ΔG is **negative** (ΔG < 0). - A process is **non-spontaneous** if ΔG is **positive** (ΔG > 0). - At **equilibrium**, ΔG is equal to **zero** (ΔG = 0). ### Step 3: Evaluate the Statements Now, let's evaluate the given statements regarding ΔG: 1. If ΔG is negative, the process is non-spontaneous. **(Incorrect)** 2. If ΔG is positive, the process is spontaneous. **(Incorrect)** 3. If ΔG is negative, the process is spontaneous. **(Correct)** 4. For equilibrium, ΔG must be equal to 0. **(Correct)** ### Conclusion From the analysis, the correct statements regarding Gibbs energy change are: - If ΔG is negative, the process is spontaneous. - For equilibrium, ΔG must be equal to 0. Thus, the correct answer is option C: "If ΔG is negative, the process is spontaneous."
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