Home
Class 11
CHEMISTRY
At dynamic equilibrium the reaction on b...

At dynamic equilibrium the reaction on both sides occur at the same rate and the mass on both sides of the equilibrium does not undergo any change. This condition can be achieved only when the value of `DeltaG` is

A

`-1`

B

`+1`

C

`+2`

D

0

Text Solution

AI Generated Solution

The correct Answer is:
To determine the value of ΔG (Gibbs free energy) at dynamic equilibrium, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Dynamic Equilibrium**: - At dynamic equilibrium, the rate of the forward reaction equals the rate of the reverse reaction. This means that the concentrations of reactants and products remain constant over time, even though both reactions are still occurring. 2. **Gibbs Free Energy (ΔG)**: - Gibbs free energy (ΔG) is a thermodynamic potential that can be used to predict the direction of a chemical reaction. The sign of ΔG indicates whether a reaction is spontaneous or non-spontaneous. 3. **Conditions for Spontaneity**: - If ΔG < 0, the reaction is spontaneous (it can proceed without external energy). - If ΔG > 0, the reaction is non-spontaneous (it requires external energy to proceed). 4. **Equilibrium Condition**: - At equilibrium, the system is in a state where the forward and reverse reactions occur at the same rate. This implies that there is no net change in the concentrations of reactants and products. 5. **Value of ΔG at Equilibrium**: - At dynamic equilibrium, the system is in a stable state where the energy change associated with the system is zero. Therefore, the value of ΔG at equilibrium is: \[ \Delta G = 0 \] 6. **Conclusion**: - Thus, the condition of dynamic equilibrium can only be achieved when ΔG is equal to zero. ### Final Answer: The value of ΔG at dynamic equilibrium is **0**. ---

To determine the value of ΔG (Gibbs free energy) at dynamic equilibrium, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Dynamic Equilibrium**: - At dynamic equilibrium, the rate of the forward reaction equals the rate of the reverse reaction. This means that the concentrations of reactants and products remain constant over time, even though both reactions are still occurring. 2. **Gibbs Free Energy (ΔG)**: ...
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    NCERT FINGERTIPS ENGLISH|Exercise HIGHER ORDER THINKING SKILLS|8 Videos
  • THERMODYNAMICS

    NCERT FINGERTIPS ENGLISH|Exercise NCERT EXEMPLAR PROBLEMS|11 Videos
  • THE S-BLOCK ELEMENTS

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos

Similar Questions

Explore conceptually related problems

The equilibrium state can be attained from both sides of the chemical reaction.

When patches of phloem occur on both sides of xylem, then vascular bundle is called as

Assertion:- The reaction quotient Q, has the same presentation form as the equilibrium constant K and Q is evaluated using any given concentrations of the species involved in the reaction, and not necesssarily equilibrium concenetrations. Reason:- If the numerical value of Q is not the same as the value of equilibrium constant, that time reaction will never proceed.

The following are some statements about chemical equilibrium. (A) The rate of forward reaction is equal to the rate of backward reation. (B) The chemical equilibrium can be established from reactant side only. (C) The concentration of the reactants and products remain same with time. The correct statements are

Read the following paragraph and answer the questions given below , Stable equilibrium is of various types . Mechanical equilibrium is achieved when all particles are at rest and total potential energy of the system is minimum . At any stage where particles are at rest but the system is not at stable equilibrium as it can reduce its potential energy by reverting to another position, is called metastable equilibrium . Thermal equilibrium is result from the absence of temperature gradients in the system. Chemical equilibrium is obtained when no further reaction occurs between reacting substances, i.e forward and reverse rates of reaction are equal. When steam with solid iron at high temperature Fe_3O_4(s) and hydrogen gas are produced . But the reaction never goes to completion. This is because as the products are formed the reaction proceeds in reverse direction and when rate of reverse reaction is equal to rate of forward reaction , the concentration of reactants and products become constant and equilibrium is reached. The primary objective of the passage is

Read the following paragraph and answer the questions given below , Stable equilibrium is of various type . Mechanical equilibrium is achieved when all particles are at rest and total potential energy of the system is minimum . At any stage where particles are at rest but the system is not at stabel equilibrium as it can reduce its potential energy by reverting to another position, is called metastable equilibrium . Thermal equilibrium is result from the absence of temperature gradients in the system. chemical equilibrium is obtained when no further reaction occurs between reacting substances, i.e forward and reverse rates of reaction are equal. when steam with solid iron at high temperature Fe_3O_4(s) and hydrogen gas are produced . But the reaction never goes to completion. this is because as the products are formed the reaction proceeds in reverse direction and when rate of reverse reaction is equal to rate of forward reaction , the concentration of reactants and products become constant and equilibrium is reached. The correct expression for equilibrium constant of the reaction, taken as an example of chemical equilibrium in the above passage is

Read the following paragraph and answer the questions given below , Stable equilibrium is of various types . Mechanical equilibrium is achieved when all particles are at rest and total potential energy of the system is minimum . At any stage where particles are at rest but the system is not at stable equilibrium as it can reduce its potential energy by reverting to another position, is called metastable equilibrium . Thermal equilibrium is result from the absence of temperature gradients in the system. Chemical equilibrium is obtained when no further reaction occurs between reacting substances, i.e forward and reverse rates of reaction are equal. When steam with solid iron at high temperature Fe_3O_4(s) and hydrogen gas are produced . But the reaction never goes to completion. This is because as the products are formed the reaction proceeds in reverse direction and when rate of reverse reaction is equal to rate of forward reaction , the concentration of reactants and products become constant and equilibrium is reached. When two reactants (A) and (B) are mixed to give products (C) and (D) the concentration quotient (Q) at initial stage of the reaction

Read the following paragraph and answer the questions given below , Stable equilibrium is of various types . Mechanical equilibrium is achieved when all particles are at rest and total potential energy of the system is minimum . At any stage where particles are at rest but the system is not at stable equilibrium as it can reduce its potential energy by reverting to another position, is called metastable equilibrium . Thermal equilibrium is result from the absence of temperature gradients in the system. Chemical equilibrium is obtained when no further reaction occurs between reacting substances, i.e forward and reverse rates of reaction are equal. when steam with solid iron at high temperature Fe_3O_4(s) and hydrogen gas are produced . But the reaction never goes to completion. this is because as the products are formed the reaction proceeds in reverse direction and when rate of reverse reaction is equal to rate of forward reaction , the concentration of reactants and products become constant and equilibrium is reached. When a matchbox is balanced on its edge, it is unstable and will tumble to a more stable position resting on its face so as to acquire minimum potential energy. This is an example of

A body of mass 0.10kg is attached to vertical massless spring with force constant 4.0 xx 10^(3)N//m . The body is displaced 10.0cm from its equilibrium position and released. How much time elapses as the body moves from a point 8.0 cm on one side of the equilibrium position to a point 6.0cm on the same side of the equilibrium position ?

A mass M is attached to a horizontal spring of force constant k fixed one side to a rigid support as shown in figure. The mass oscillates on a frictionless surface with time period T and amplitude A. When the mass M is in equilibrium position, another mass m is gently placed on it. When will be the new amplitude of ocillation?

NCERT FINGERTIPS ENGLISH-THERMODYNAMICS-Assertion And Reason
  1. At dynamic equilibrium the reaction on both sides occur at the same ra...

    Text Solution

    |

  2. Assertion : The presence of reactants in a closed vessel made of condu...

    Text Solution

    |

  3. Assertion : In adiabatic system, DeltaU=w(ad.) Reason : In adiabatic...

    Text Solution

    |

  4. Assertion (A): Internal energy change in a cyclic process is zero. ...

    Text Solution

    |

  5. Assertion : Work done during free expansion of an ideal gas whether re...

    Text Solution

    |

  6. Assertion : The difference between DeltaH and DeltaU is not significan...

    Text Solution

    |

  7. Assertion : For the change, H(2)O((l))rarr H(2)O((s)),DeltaH=DeltaU. ...

    Text Solution

    |

  8. Assertion : DeltaH for an exothermic reaction is negative nad for an e...

    Text Solution

    |

  9. Assertion : The enthalpy change for the reaction CaO((s))+CO(2(g)) rar...

    Text Solution

    |

  10. Assertion : The solubility of most salts in water increases with rise ...

    Text Solution

    |

  11. Assertion : Heat of neutralisation of HNO(3) and NaOH is same as that ...

    Text Solution

    |

  12. Assertion : Heat added to a system at lower temperature causes greate...

    Text Solution

    |

  13. Assertion : In the proces, H(2(g)) rarr 2H((g)).entropy increases. R...

    Text Solution

    |

  14. Assertion : An exothermic process which is non-spontaneous at high tem...

    Text Solution

    |

  15. Assertion : If both DeltaH^(@) and DeltaS^(@) are positive then reacti...

    Text Solution

    |

  16. Assertion : Third law of thermodynamics is confined to pure crystallin...

    Text Solution

    |