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The pressure-volume work for an ideal ga...

The pressure-volume work for an ideal gas can be calculated by using the expression `W=-int_(V_(i))^(V_(f))P_(ex)dV.` The work can also be calculated from the pV - plot by using the area under the curve within the specified limits. When an ideal gas is compressed (i) reversibly or (ii) irreversibly from volume `V_(i)` to `V_(f)`. Choose the correct option.

A

`W_("reversible")=W_("irreversible")`

B

`W_("reversible")ltW_("irreversible")`

C

`W_("reversible") gt W_("irreversible")`

D

`W_("reversible")=W_("irreversible")+P_(ex)DeltaV`

Text Solution

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The correct Answer is:
To solve the problem regarding the work done on an ideal gas during reversible and irreversible compression, we can follow these steps: ### Step 1: Understand the Work Done Expression The work done on an ideal gas during compression can be expressed mathematically as: \[ W = -\int_{V_i}^{V_f} P_{ex} \, dV \] Where: - \( W \) is the work done, - \( V_i \) is the initial volume, - \( V_f \) is the final volume, - \( P_{ex} \) is the external pressure. ### Step 2: Analyze the PV Diagram Draw a Pressure-Volume (PV) diagram for both reversible and irreversible compression. - For reversible compression, the process is carried out slowly, allowing the system to remain in equilibrium. The curve will be smooth and continuous. - For irreversible compression, the process occurs rapidly, and the path taken will be different, typically resulting in a steeper curve. ### Step 3: Identify the Areas Under the Curves In the PV diagram: - The area under the curve for reversible compression represents the work done \( W_{reversible} \). - The area under the curve for irreversible compression represents the work done \( W_{irreversible} \). ### Step 4: Compare the Work Done Since both processes start at the same initial volume \( V_i \) and end at the same final volume \( V_f \): - The area under the curve for irreversible compression is generally larger than that for reversible compression due to the higher external pressure acting over a larger volume change. - Thus, we can conclude that: \[ W_{irreversible} > W_{reversible} \] ### Step 5: Choose the Correct Option Based on the analysis, the correct option is: - **W irreversible is more than W reversible.** ### Final Answer The correct option is **W irreversible > W reversible.** ---

To solve the problem regarding the work done on an ideal gas during reversible and irreversible compression, we can follow these steps: ### Step 1: Understand the Work Done Expression The work done on an ideal gas during compression can be expressed mathematically as: \[ W = -\int_{V_i}^{V_f} P_{ex} \, dV \] Where: - \( W \) is the work done, - \( V_i \) is the initial volume, ...
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