Home
Class 11
CHEMISTRY
In the following reaction: 2NO((g))+Cl...

In the following reaction:
`2NO_((g))+Cl_(2(g))hArr2NOCl_((g))`
it is observed that equilibrium is not attained and the rate of forward reaction is greater than rate of backward reaction. Which of the following is true for the reaction ? (A) K p = Q p (B) Q p > K p (C) Q p < K p (D) Q p = 0

A

`K_(p)=Q_(p)`

B

`Q_(p)gtK_(p)`

C

`Q_(p)ltK_(p)`

D

`Q_(p)=0`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given reaction and the information provided about the rates of the forward and backward reactions. ### Step-by-Step Solution: 1. **Understanding the Reaction**: The reaction given is: \[ 2NO_{(g)} + Cl_{2(g)} \rightleftharpoons 2NOCl_{(g)} \] This is a reversible reaction where nitrogen monoxide (NO) and chlorine (Cl2) react to form nitrosyl chloride (NOCl). 2. **Equilibrium Concept**: In a reversible reaction, equilibrium is attained when the rate of the forward reaction equals the rate of the backward reaction. At this point, the concentrations of reactants and products remain constant. 3. **Given Information**: - It is stated that equilibrium is not attained. - The rate of the forward reaction is greater than the rate of the backward reaction. 4. **Implications of the Given Information**: Since the forward reaction is faster, this means that the concentration of products (NOCl) is increasing while the concentration of reactants (NO and Cl2) is decreasing. Therefore, we can conclude that the reaction is still moving towards the formation of more products. 5. **Understanding Reaction Quotient (Qp)**: The reaction quotient \( Q_p \) is defined as: \[ Q_p = \frac{(P_{NOCl})^2}{(P_{NO})^2 \cdot (P_{Cl2})} \] where \( P \) represents the partial pressures of the respective gases. 6. **Comparing Qp and Kp**: - \( K_p \) is the equilibrium constant, which is a constant value at a given temperature when the system is at equilibrium. - Since the forward reaction is favored and products are being formed, \( Q_p \) must be less than \( K_p \) because equilibrium has not been reached yet. 7. **Conclusion**: Since the concentration of products is increasing and the concentration of reactants is decreasing, we can conclude that: \[ Q_p < K_p \] Therefore, the correct answer is: **(C) \( Q_p < K_p \)**.

To solve the problem, we need to analyze the given reaction and the information provided about the rates of the forward and backward reactions. ### Step-by-Step Solution: 1. **Understanding the Reaction**: The reaction given is: \[ 2NO_{(g)} + Cl_{2(g)} \rightleftharpoons 2NOCl_{(g)} ...
Promotional Banner

Topper's Solved these Questions

  • EQUILIBRIUM

    NCERT FINGERTIPS ENGLISH|Exercise HOTS|6 Videos
  • EQUILIBRIUM

    NCERT FINGERTIPS ENGLISH|Exercise EXEMPLAR PROBLEMS|19 Videos
  • ENVIRONMENTAL CHEMISTRY

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos
  • HYDROCARBONS

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos

Similar Questions

Explore conceptually related problems

In the following reaction : 2SO_(2)(g)+O_(2)(g) hArr 2SO_(3)(g) the equilibrium is not attained . The rate of forward reaction is greater than that of backward. Thus, which of the following is the correct relation between K_(p) and Q_(p) ?

Mass action rato or reaction quotient Q for a reaction can be calculate using the law of masss action A(g)+B(g) hArr C(g)+D(g) Q=([C][D])/([A][B]) The value of Q decides whether the reaction is at equilibrium or not. At equilibrium, Q=K For an equilibrium process, Q ne K when Q gt K , reaction will favour backward direction and when Q lt K , it will favour direction. Answer the following questions: In the following reaction: 2SO_(2)(g)+O_(2)(g) hArr 2SO_(3)(g) the equilibrium is not attained. The rate of forward reaction is greater than that of backward reaction. Thus, which of the following is the correct relation between K_(p) and Q_(p) ?

For the reaction, CO_((g))+Cl_(2(g))hArrCoCl_(2(g)) , the value of K_(p)//K_(c) is equal to

For the reaction, N_(2)(g)+3H_(2)(g) hArr 2NH_(3)(g) , the units of K_(p) are …………

At equilibrium for a reaction A harr B . correct representation is { r_f = rate of forward reaction, r_b = rate of backward reaction}

For the reaction , CO(g)+Cl(g)hArrCOCl_2(g) then K_p//K_c is equal to :

For the following equilibrium N_(2)O_(4)(g)hArr 2NO_(2)(g) K_(p) is found to be equal to K_(c) . This is attained when :

In the reaction PCl_(5)(g)hArrPCl_(3)(g)+Cl_(2)(g) a graph in plotted to show the variation of rate of forward and backward reactions against time. Which of the following is correct? QgtK Q=K QltK

For the reactions, CO(g) +Cl_2( g) hArr COCl_2(g), " the " (K_P)/(K_c) is equal to

The yield of product in the reaction 2A_((g)) + B_((g)) hArr 2C_((g)) + Q K J would be lower at :

NCERT FINGERTIPS ENGLISH-EQUILIBRIUM -Assertion And Reason
  1. In the following reaction: 2NO((g))+Cl(2(g))hArr2NOCl((g)) it is o...

    Text Solution

    |

  2. Assertion : When ice and water are kept in a perfectly insulated therm...

    Text Solution

    |

  3. Assertion : The equilibrium constant for the reverse reaction is equa...

    Text Solution

    |

  4. Assertion : For the reaction : N(2(g))+3H(2(g))hArr2NH(3(g)),K(p)=K(c)...

    Text Solution

    |

  5. Assertion : K(p) can be less than, greater than or equal to K(c) Rea...

    Text Solution

    |

  6. Assertion : If reaction quotient, Q(c) for a particular reaction is gr...

    Text Solution

    |

  7. Assertion : In the dissociation of PCl(5) at constant pressure and tem...

    Text Solution

    |

  8. Assertion : Weak acids have very strong conjugate bases while strong a...

    Text Solution

    |

  9. Assertion :- A solution of NH(4)Cl in water is acidic in nature. ...

    Text Solution

    |

  10. Statement: The pH of an aqueous solution of acetic acid remains unchan...

    Text Solution

    |

  11. Assertion : Higher order ionization constants (K(a(2)),K(a(3))) are sm...

    Text Solution

    |

  12. Assertion : Benzoic acid is stronger acid than acetic acid. Reason ...

    Text Solution

    |

  13. Assertion : The strength of haloacids increases in the order : HIltltH...

    Text Solution

    |

  14. Assertion : The pH of NH(4)Cl solution in water is less than 7 and pH ...

    Text Solution

    |

  15. Assertion : pH of the buffer solution is not affected by dilution. ...

    Text Solution

    |

  16. Assertion : The solubility of salts of weak acids like phosphates decr...

    Text Solution

    |