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Dissociation constant of CH(3)COOH and ...

Dissociation constant of `CH_(3)COOH` and ` NH_(4)OH` in squeous solution are `10^(-5)` if pH of a `CH_(3)COOH` solution is 3, what will be the pH of `NH_(4)OH` ?

A

`3.0`

B

`4.0`

C

`10.0`

D

`11.0`

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The correct Answer is:
To solve the problem, we need to find the pH of the NH₄OH solution given the pH of the CH₃COOH solution and the fact that both have the same dissociation constant (Kₐ = K_b = 10⁻⁵). ### Step-by-Step Solution: 1. **Identify the given information:** - The dissociation constant (Kₐ) of CH₃COOH is \(10^{-5}\). - The pH of the CH₃COOH solution is 3. - We need to find the pH of the NH₄OH solution. 2. **Calculate the pOH from the pH of CH₃COOH:** - We know the relationship between pH and pOH: \[ \text{pH} + \text{pOH} = 14 \] - Given that pH = 3: \[ \text{pOH} = 14 - \text{pH} = 14 - 3 = 11 \] 3. **Relate the pOH of NH₄OH to its pH:** - Since we have calculated the pOH of the NH₄OH solution, we can now find its pH using the same relationship: \[ \text{pH} + \text{pOH} = 14 \] - Substituting the value of pOH: \[ \text{pH} = 14 - \text{pOH} = 14 - 11 = 3 \] 4. **Conclusion:** - The pH of the NH₄OH solution is 3. ### Final Answer: The pH of the NH₄OH solution is 11.

To solve the problem, we need to find the pH of the NH₄OH solution given the pH of the CH₃COOH solution and the fact that both have the same dissociation constant (Kₐ = K_b = 10⁻⁵). ### Step-by-Step Solution: 1. **Identify the given information:** - The dissociation constant (Kₐ) of CH₃COOH is \(10^{-5}\). - The pH of the CH₃COOH solution is 3. - We need to find the pH of the NH₄OH solution. ...
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NCERT FINGERTIPS ENGLISH-EQUILIBRIUM -Assertion And Reason
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