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At 500 K, equlibrium constant, K(c) for ...

At 500 K, equlibrium constant, `K_(c)` for the following reaction is 5.
`1//2 H_(2)(g)+ 1//2(g)hArr HI (g)`
What would be the equilibrium constant `K_(c)` for the reaction `2HI(g)hArrH_(2)(g)+l_(2)(g)`

A

0.04

B

0.4

C

25

D

2.5

Text Solution

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The correct Answer is:
To solve the problem, we need to find the equilibrium constant \( K_c \) for the reaction: \[ 2 \text{HI}(g) \rightleftharpoons \text{H}_2(g) + \text{I}_2(g) \] given that the equilibrium constant \( K_c \) for the reaction: \[ \frac{1}{2} \text{H}_2(g) + \frac{1}{2} \text{I}_2(g) \rightleftharpoons \text{HI}(g) \] is 5 at 500 K. ### Step-by-Step Solution: 1. **Write the given reaction and its equilibrium constant:** \[ \frac{1}{2} \text{H}_2(g) + \frac{1}{2} \text{I}_2(g) \rightleftharpoons \text{HI}(g) \quad K_c = 5 \] 2. **Reverse the reaction:** When we reverse a reaction, the equilibrium constant for the reverse reaction is the reciprocal of the original equilibrium constant. \[ \text{HI}(g) \rightleftharpoons \frac{1}{2} \text{H}_2(g) + \frac{1}{2} \text{I}_2(g) \quad K_c' = \frac{1}{5} \] 3. **Multiply the reversed reaction by 2:** We now multiply the entire reversed reaction by 2 to obtain the desired reaction. \[ 2 \text{HI}(g) \rightleftharpoons \text{H}_2(g) + \text{I}_2(g) \] When we multiply a reaction by a coefficient, we raise the equilibrium constant to the power of that coefficient. \[ K_c'' = \left( K_c' \right)^2 = \left( \frac{1}{5} \right)^2 \] 4. **Calculate the new equilibrium constant:** \[ K_c'' = \frac{1}{25} = 0.04 \] 5. **Final answer:** The equilibrium constant \( K_c \) for the reaction \( 2 \text{HI}(g) \rightleftharpoons \text{H}_2(g) + \text{I}_2(g) \) is \( 0.04 \).

To solve the problem, we need to find the equilibrium constant \( K_c \) for the reaction: \[ 2 \text{HI}(g) \rightleftharpoons \text{H}_2(g) + \text{I}_2(g) \] given that the equilibrium constant \( K_c \) for the reaction: \[ \frac{1}{2} \text{H}_2(g) + \frac{1}{2} \text{I}_2(g) \rightleftharpoons \text{HI}(g) \] ...
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