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Consider the following reaction, {:(CH...

Consider the following reaction,
`{:(CHO" "COO^(-)),("| "+OH^(-) rarr "|"),(CHO" "CH_(2)OH):}`
Select the incorrect statement.

A

It is not a disproportionation reaction.

B

It is intramolecular redox reaction.

C

`OH^(-)` is a reducing as well as oxidising agent.

D

`{:(CHO),("|"),(CHO):}` is a reducing as well as oxidising agent.

Text Solution

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The correct Answer is:
To solve the question regarding the given reaction and select the incorrect statement, let's analyze the reaction step by step. ### Step 1: Identify the Reactants and Products The reaction provided is: \[ \text{CHO} \, \text{COO}^- + \text{OH}^- \rightarrow \text{CHO} \, \text{CH}_2\text{OH} \] Here, we have: - **CHO** (an aldehyde) - **COO^-** (the carboxylate ion) - **OH^-** (hydroxide ion) - **CH2OH** (an alcohol) ### Step 2: Determine Oxidation and Reduction In this reaction: - The aldehyde group (CHO) is being oxidized to the carboxylate ion (COO^-). - The hydroxide ion (OH^-) is involved in the reduction of another aldehyde group (CHO) to form the alcohol (CH2OH). ### Step 3: Classify the Reaction Since one part of the molecule is being oxidized while another part is being reduced, this indicates that: - This is an **intramolecular redox reaction** because both oxidation and reduction occur within the same molecule. - It is also a **disproportionation reaction** because the same species (the aldehyde) is undergoing both oxidation and reduction. ### Step 4: Analyze the Statements Now, let's evaluate the statements provided in the question: 1. **Statement 1**: It is not a disproportionation reaction. - **Incorrect**: This is a disproportionation reaction since one species is undergoing both oxidation and reduction. 2. **Statement 2**: It is an intramolecular redox reaction. - **Correct**: This is indeed an intramolecular redox reaction. 3. **Statement 3**: OH is a reducing as well as an oxidizing agent. - **Correct**: The hydroxide ion can act as both a reducing agent (in the reduction of CHO to CH2OH) and an oxidizing agent (in the oxidation of another CHO). 4. **Statement 4**: This molecule is a reducing as well as an oxidizing agent. - **Correct**: The molecule involved is acting as both a reducing agent (by reducing another species) and an oxidizing agent (by being oxidized itself). ### Conclusion Based on the analysis: - The **incorrect statement** is **Statement 1**: It is not a disproportionation reaction.

To solve the question regarding the given reaction and select the incorrect statement, let's analyze the reaction step by step. ### Step 1: Identify the Reactants and Products The reaction provided is: \[ \text{CHO} \, \text{COO}^- + \text{OH}^- \rightarrow \text{CHO} \, \text{CH}_2\text{OH} \] Here, we have: - **CHO** (an aldehyde) ...
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