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which of the following statements is not...

which of the following statements is not correct about the reaction given below?
`K_(4)[Fe(CN)_(6)]overset("Oxidation")rarrFe^(3+)+CO_(2)+NO_(3)^(ө)`

A

Fe is oxidised from `Fe^(2+)` to `Fe^(3+)`.

B

Carbon is oxidised from `C^(2+)` to `C^(4+)`.

C

N is oxidised from `N^(3-)` to `N^(5+)`.

D

Carbon is not oxidised.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is not correct about the given reaction \( K_4[Fe(CN)_6] \) undergoing oxidation to produce \( Fe^{3+} + CO_2 + NO_3^- \), we can analyze the oxidation states of the elements involved, particularly focusing on carbon in the cyanide complex. ### Step-by-step Solution: 1. **Identify the oxidation state of carbon in \( K_4[Fe(CN)_6] \)**: - The cyanide ion \( CN^- \) consists of carbon (C) and nitrogen (N). - The oxidation state of nitrogen in \( CN^- \) is \(-3\). - Let the oxidation state of carbon be \( x \). The equation for the oxidation state of the cyanide ion can be set up as: \[ x + (-3) = -1 \] - Solving for \( x \): \[ x - 3 = -1 \implies x = +2 \] - Therefore, the oxidation state of carbon in \( K_4[Fe(CN)_6] \) is \( +2 \). 2. **Determine the oxidation state of carbon in \( CO_2 \)**: - In carbon dioxide \( CO_2 \), the oxidation state of carbon can be calculated as follows: \[ x + 2(-2) = 0 \] - Solving for \( x \): \[ x - 4 = 0 \implies x = +4 \] - Therefore, the oxidation state of carbon in \( CO_2 \) is \( +4 \). 3. **Calculate the change in oxidation state of carbon**: - The change in oxidation state of carbon from \( K_4[Fe(CN)_6] \) to \( CO_2 \) is: \[ +2 \text{ (in } K_4[Fe(CN)_6]) \text{ to } +4 \text{ (in } CO_2) \] - The change is: \[ +4 - (+2) = +2 \] - This indicates that carbon is oxidized from \( +2 \) to \( +4 \). 4. **Conclusion**: - Since carbon is indeed oxidized from \( +2 \) to \( +4 \), any statement claiming that carbon is not oxidized would be incorrect. - Therefore, the statement "Carbon is not oxidized" is the one that is not correct. ### Final Answer: The statement that is not correct about the reaction is: **"Carbon is not oxidized."**

To determine which statement is not correct about the given reaction \( K_4[Fe(CN)_6] \) undergoing oxidation to produce \( Fe^{3+} + CO_2 + NO_3^- \), we can analyze the oxidation states of the elements involved, particularly focusing on carbon in the cyanide complex. ### Step-by-step Solution: 1. **Identify the oxidation state of carbon in \( K_4[Fe(CN)_6] \)**: - The cyanide ion \( CN^- \) consists of carbon (C) and nitrogen (N). - The oxidation state of nitrogen in \( CN^- \) is \(-3\). - Let the oxidation state of carbon be \( x \). The equation for the oxidation state of the cyanide ion can be set up as: ...
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