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E^(@) for CL(2)//Cl^(-)=+1.36,I(2)//I^(-...

`E^(@)` for `CL_(2)//Cl^(-)=+1.36,I_(2)//I^(-)=+0.53,Ag^(+)//Ag=+0.79,Na^(+)//Na=-2.71 and Li^(+)//Li=-3.04V`. What is the order of decreasing reducing sterngth for these species?

A

`Li gt Cl^(-) gt Ag gt I^(-) gt Na`

B

`Li gt Na gt I^(-) gt Ag gt Cl^-`

C

`Cl^(-) gt Ag gt I^(-) gt Na gt Li`

D

`Na gt Li gt Ag gt Cl^(-) gt I^(-)`

Text Solution

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The correct Answer is:
To determine the order of decreasing reducing strength for the given species based on their standard reduction potentials (E°), we need to follow these steps: ### Step 1: List the Standard Reduction Potentials We have the following standard reduction potentials: - \( E^\circ \) for \( Cl_2/Cl^- = +1.36 \, V \) - \( E^\circ \) for \( I_2/I^- = +0.53 \, V \) - \( E^\circ \) for \( Ag^+/Ag = +0.79 \, V \) - \( E^\circ \) for \( Na^+/Na = -2.71 \, V \) - \( E^\circ \) for \( Li^+/Li = -3.04 \, V \) ### Step 2: Understand Reducing Strength Reducing strength refers to the ability of a species to get oxidized (lose electrons) and, in turn, reduce other species. The species with the lowest standard reduction potential will have the highest tendency to get oxidized. ### Step 3: Arrange the Potentials in Increasing Order To find the order of decreasing reducing strength, we need to arrange the standard reduction potentials from the lowest to the highest: 1. \( Li^+/Li = -3.04 \, V \) (lowest) 2. \( Na^+/Na = -2.71 \, V \) 3. \( I_2/I^- = +0.53 \, V \) 4. \( Ag^+/Ag = +0.79 \, V \) 5. \( Cl_2/Cl^- = +1.36 \, V \) (highest) ### Step 4: Determine the Order of Reducing Strength Based on the arrangement, the order of decreasing reducing strength (from highest to lowest) is: 1. \( Li \) (highest reducing strength) 2. \( Na \) 3. \( I^- \) 4. \( Ag \) 5. \( Cl^- \) (lowest reducing strength) ### Final Answer The order of decreasing reducing strength for the species is: **Li > Na > I^- > Ag > Cl^-**

To determine the order of decreasing reducing strength for the given species based on their standard reduction potentials (E°), we need to follow these steps: ### Step 1: List the Standard Reduction Potentials We have the following standard reduction potentials: - \( E^\circ \) for \( Cl_2/Cl^- = +1.36 \, V \) - \( E^\circ \) for \( I_2/I^- = +0.53 \, V \) - \( E^\circ \) for \( Ag^+/Ag = +0.79 \, V \) - \( E^\circ \) for \( Na^+/Na = -2.71 \, V \) ...
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The E^(Theta) for Cl_(2)//Cl^(-) is +1.36 for I_(2)//I^(-) is +0.53, " for " Ag^(+)//Ag is +0.79, Na^(+)//Na is -2.71 and for Li^(+)//Li is -3.04 Arrange the following ionic spects in decreasing order of reducing strength: I^(-), Ag, Cl^(-), Li, Na

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Using the data given below: E_(Cr_(2)O_(7)^(2-)|Cr^(3+))^(@)=1.33V E_(Cl_(2)|Cl^(-))^(@)=1.36V E_(MnO_(4)^(-)|Mn^(2+))^(@)=1.51V E_(Cr^(3+)|Cr)=-0.74V In which option the order of reducing power is correct?

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Given E_(Ag^(+)//Ag)^(@)=0.80V , E_(Mg^(2+)//Mg)^(@)=-2.37V , E_(Cu^(2+)//Cu)^(@)=0.79 E_(Hg^(2+)//Hg)^(@)=1.71V Which of the following statements is/are correct?

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