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The properties of lithium are similar to...

The properties of lithium are similar to those of Mg. This is because

A

both have nearly the same size

B

both have similar electronic configuration

C

both have nearly same charge to size ratio

D

Both are found together in nature

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The correct Answer is:
To understand why the properties of lithium are similar to those of magnesium, we can follow these steps: ### Step 1: Identify the Elements - We are comparing lithium (Li) and magnesium (Mg). ### Step 2: Understand the Concept of Diagonal Relationship - A diagonal relationship in the periodic table refers to the similarity in properties between elements that are positioned diagonally from each other. In this case, lithium is in Group 1 (alkali metals), and magnesium is in Group 2 (alkaline earth metals). ### Step 3: Charge and Size Ratio - Lithium has a charge of +1, while magnesium has a charge of +2. - The size of lithium is smaller than that of magnesium. The atomic radius of lithium is about 152 pm, and that of magnesium is about 160 pm. ### Step 4: Calculate Charge to Size Ratio - The charge to size ratio can be understood as the charge of the ion divided by its size (radius). - For lithium: Charge/Size = +1 / 152 pm - For magnesium: Charge/Size = +2 / 160 pm - Although the charges are different, the ratio of charge to size for both elements is similar because the size of magnesium is nearly double that of lithium. ### Step 5: Conclusion - Because both lithium and magnesium have similar charge to size ratios, they exhibit similar chemical and physical properties. This similarity is the reason for their diagonal relationship. ### Final Answer The properties of lithium are similar to those of magnesium because both have nearly the same charge to size ratio. ---
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NCERT FINGERTIPS ENGLISH-THE S-BLOCK ELEMENTS-Assertion And Reason
  1. The properties of lithium are similar to those of Mg. This is because

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  2. Assertion: Elements of group 1 are called 'alkali metals'. Reason: A...

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  3. Assertion: Lithium resembles magnesium diagonally placed in next group...

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  4. Assertion: Alkali metals are obtained by electrolysis of molten salt a...

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  5. Assertion: Lithium salts are mostly hydrated. Reason: The hydration ...

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  6. Assertion: The melting and boiling points of the alkali metals are low...

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  7. Assertion: Lithium fluoride is most covalent in nature. Reason: Smal...

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  8. Assertion: The carbonate of lithium decomposes easily on heating. Re...

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  9. Assertion : Super-oxides of alkali metals are para-magnetic. Reason ...

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  10. Assertion: Be and Mg do not impat characteristic colour to the flame. ...

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  11. Assertion: The fluorides of alkaline earth metals are relatively less ...

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  12. Assertion: Be is readily attacked by acids. Reason: Be shows diagona...

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  13. Assertion: Alkaline earth metal oxides are quite stable to heat. Rea...

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  14. Assertion: BeSO(4) and MgSO(4) are insoluble in water. Reason: Be^(2...

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  15. Assertion: CaCO(3) is prepared by passing carbon dioxide gas through s...

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  16. Assertion: For biological functions in human body, barium is not requi...

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