Home
Class 11
CHEMISTRY
When alkaline earth metals dissolve ini ...

When alkaline earth metals dissolve ini ammonia, they form coloured solution like alkali metals. Which of the following observations regarding the reaction are correct?
(i) Dilute solutions are bright blue in colour due to solvated electrons.
(ii) These solutions decompose to form amides and hydrogen.
(iii) From this solution the ammoniates
`[M(NH_(3))_(6)]^(2+)` can be recovered by evaporation.

A

Only (i) and (ii)

B

Only (i), (ii) and (iii)

C

Only (ii) and (iii)

D

Only (i)

Text Solution

Verified by Experts

The correct Answer is:
B

All the observations are correct.
`Mto M^(2+) +2e^(-)`
`2NH_(3)+2e^(-) to 2NH_(2)^(-)+H_(2)`
`M^(2+)+2NH_(2)^(-) to M(NH_(2))_(2) overset("evaporation")to [M(NH_(3))_(6)]^(2+)`
`[M(NH_(3))_(6)]^(2+) to M(NH_(2))_(2)+4NH_(3)+H_(2)`
Promotional Banner

Topper's Solved these Questions

  • THE S-BLOCK ELEMENTS

    NCERT FINGERTIPS ENGLISH|Exercise Higher Order Thinkin Skills|10 Videos
  • THE S-BLOCK ELEMENTS

    NCERT FINGERTIPS ENGLISH|Exercise Exemplar Problems|21 Videos
  • THE P-BLOCK ELEMENTS

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos
  • THERMODYNAMICS

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos

Similar Questions

Explore conceptually related problems

Alkali earth metals in liq. NH_(3) produce a blue coloured solution, due to

When alkali metal is dissolved in liquid NH_3 the blue colour of the dilute solution changes to bronze colour due to

The blue colour of solution of ammonia and alkali metals is due to which species?

Sodium metal dissolves in liquid ammonia and forms a deep blue solution. The colour is due to absorption of light by :

When an alkali metal dissolves in liquid ammonia the solution can acquire different colours. Explain the reasons for this type of colour change.

Assertion (A): Alkali metals dissolve in liquid ammoia to give blue solution. Reason (R ): Alkali metals in liquid ammonia give solvated species of the type [e^(-)(NH_(3))_(y)]^(Θ) .

Assertion (A): Caesium metal when dissolved in liquid amtmonia forms a blue-coloured solution. Reason(R ): The blue solution is a good conductor of electricity.

When a metal of group 1 was dissolved in liquid ammonia, the following observations were obtained (a) Blue solution was obtained initially. On concentrating the solution, blue colour changed to bronze colour.How do you account for the blue colour of the solution? Given the name of the product formed on keeping the solution for some time.

The alkali metals dissolve in ammonia to give a deep blue solution which is cnducting in nature. M+(x+y)NH_(3)to[M(NH_(3))_(x)]^(2+)+2[e(NH_(3))_(y)]^(-) which of the followin is not true about the solutions of alkali metals in liquid ammonia?

Which of the following pairs will give displacement reactions? (i) NaCl solution and copper metal (ii) MgCl_(2) solution and aluminium metal (iii) FeSO_(4) solution and silver metal (iv) AgNO_(3) solution and copper metal

NCERT FINGERTIPS ENGLISH-THE S-BLOCK ELEMENTS-Assertion And Reason
  1. When alkaline earth metals dissolve ini ammonia, they form coloured so...

    Text Solution

    |

  2. Assertion: Elements of group 1 are called 'alkali metals'. Reason: A...

    Text Solution

    |

  3. Assertion: Lithium resembles magnesium diagonally placed in next group...

    Text Solution

    |

  4. Assertion: Alkali metals are obtained by electrolysis of molten salt a...

    Text Solution

    |

  5. Assertion: Lithium salts are mostly hydrated. Reason: The hydration ...

    Text Solution

    |

  6. Assertion: The melting and boiling points of the alkali metals are low...

    Text Solution

    |

  7. Assertion: Lithium fluoride is most covalent in nature. Reason: Smal...

    Text Solution

    |

  8. Assertion: The carbonate of lithium decomposes easily on heating. Re...

    Text Solution

    |

  9. Assertion : Super-oxides of alkali metals are para-magnetic. Reason ...

    Text Solution

    |

  10. Assertion: Be and Mg do not impat characteristic colour to the flame. ...

    Text Solution

    |

  11. Assertion: The fluorides of alkaline earth metals are relatively less ...

    Text Solution

    |

  12. Assertion: Be is readily attacked by acids. Reason: Be shows diagona...

    Text Solution

    |

  13. Assertion: Alkaline earth metal oxides are quite stable to heat. Rea...

    Text Solution

    |

  14. Assertion: BeSO(4) and MgSO(4) are insoluble in water. Reason: Be^(2...

    Text Solution

    |

  15. Assertion: CaCO(3) is prepared by passing carbon dioxide gas through s...

    Text Solution

    |

  16. Assertion: For biological functions in human body, barium is not requi...

    Text Solution

    |