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The tendency of group 14 elements to sho...

The tendency of group 14 elements to show +2 oxidation state increases in the order of

A

`C lt Si lt Sn lt Pb lt Ge`

B

`C lt Si lt Ge lt Sn lt Pb`

C

`Ge lt Sn lt Pb lt C lt Si`

D

`Pb lt Sn lt Ge lt C lt Si`

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To determine the order of the tendency of group 14 elements to show a +2 oxidation state, we can analyze the elements in this group, which are Carbon (C), Silicon (Si), Germanium (Ge), Tin (Sn), and Lead (Pb). ### Step-by-Step Solution: 1. **Identify Group 14 Elements**: The elements in group 14 of the periodic table are Carbon (C), Silicon (Si), Germanium (Ge), Tin (Sn), and Lead (Pb). 2. **Understand Oxidation States**: Group 14 elements can exhibit oxidation states of +4 and +2. The +4 oxidation state is due to the involvement of all four valence electrons, while the +2 state arises when only the two p electrons are involved. 3. **Inert Pair Effect**: The tendency to show the +2 oxidation state increases down the group due to the inert pair effect. This effect refers to the reluctance of the s-electrons (ns²) to participate in bonding as we move down the group. 4. **Analyze Each Element**: - **Carbon (C)**: The +2 oxidation state is less stable because it prefers to form covalent bonds and typically exhibits a +4 state. - **Silicon (Si)**: Similar to Carbon, Silicon can show +2 but prefers +4. - **Germanium (Ge)**: Shows a more pronounced +2 state compared to Si and C due to the inert pair effect starting to take place. - **Tin (Sn)**: More stable in the +2 state due to the inert pair effect being more significant. - **Lead (Pb)**: The +2 oxidation state is quite stable due to the inert pair effect being fully realized. 5. **Order of Increasing Tendency**: Based on the above analysis, the order of increasing tendency to show the +2 oxidation state is: - Carbon (C) < Silicon (Si) < Germanium (Ge) < Tin (Sn) < Lead (Pb) ### Final Order: The tendency of group 14 elements to show +2 oxidation state increases in the order: **C < Si < Ge < Sn < Pb**

To determine the order of the tendency of group 14 elements to show a +2 oxidation state, we can analyze the elements in this group, which are Carbon (C), Silicon (Si), Germanium (Ge), Tin (Sn), and Lead (Pb). ### Step-by-Step Solution: 1. **Identify Group 14 Elements**: The elements in group 14 of the periodic table are Carbon (C), Silicon (Si), Germanium (Ge), Tin (Sn), and Lead (Pb). 2. **Understand Oxidation States**: Group 14 elements can exhibit oxidation states of +4 and +2. The +4 oxidation state is due to the involvement of all four valence electrons, while the +2 state arises when only the two p electrons are involved. ...
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NCERT FINGERTIPS ENGLISH-THE P-BLOCK ELEMENTS-Assertion And Reason
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  2. Assertion : In p-block elements, a lot of variation in properties of e...

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  4. Assertion:- The heavier P-block elements form storng pi- bonds. Rea...

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  5. Assertion : Boron forms only covalent compounds. , Reason : Boron ha...

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  6. Why is the atomic radius of gallium smaller than that of aluminium?

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  7. Assertion : Although aluminium is above hydrogen in electrochemical se...

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  8. Assertion : In diborane, each B atom is sp^(2) hybridised. Reason : ...

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  9. A particle (m = 3 kg) slides down a frictionless track (AOC) starting ...

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  10. Assertion : Sn in +2 oxidation state is a reducing agent while Pb in +...

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  11. Assertion : Diamond is the hardest substance on the earth. Reason : ...

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  12. Assertion : Fullerenes are the only pure form of carbon. Reason : It...

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  13. Assertion : Carbon monoxide is a poisonous gas Reason : Carbon monox...

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  14. Assertion : In CO(2) molecule C atoms undergoes sp^(2) hybridisation ...

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  15. Assertion : CO(2) is a gas at room temperature while SiO(2) is a cryst...

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  16. Assertion : Zeolites are the three-dimensional network silicates. Re...

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