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Assertion:- The heavier P-block elements...

Assertion:- The heavier P-block elements form storng `pi-` bonds.
Reasons:- The heavier elements of p-block form `dpi-p pi` or `dpi-dpi` bonds.

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To analyze the assertion and reason provided in the question, we will break down the concepts related to the bonding in heavier p-block elements step by step. ### Step 1: Understanding the Assertion The assertion states that "The heavier P-block elements form strong π bonds." - **Explanation**: Heavier p-block elements, such as sulfur, selenium, and tellurium, have the ability to form π bonds. However, the strength of these π bonds can vary based on the type of orbital overlap involved. ### Step 2: Understanding the Reason The reason states that "The heavier elements of p-block form \(d\pi-p\pi\) or \(d\pi-d\pi\) bonds." - **Explanation**: In heavier p-block elements, there are available d-orbitals that can participate in bonding. This allows for the formation of \(d\pi-p\pi\) and \(d\pi-d\pi\) bonds, which are different from the \(p\pi-p\pi\) bonds formed by lighter p-block elements like oxygen. ### Step 3: Comparing Bond Strengths Now, we need to compare the strength of these different types of bonds. - **Bond Strength**: - \(p\pi-p\pi\) bonds (formed by lighter elements) are generally stronger due to better overlap between the p-orbitals. - \(d\pi-p\pi\) and \(d\pi-d\pi\) bonds (formed by heavier elements) are generally weaker because the overlap between d-orbitals and p-orbitals is not as effective as that between p-orbitals. ### Step 4: Conclusion Based on the analysis: - The assertion that heavier p-block elements form strong π bonds is **false**. - The reason that heavier elements of the p-block form \(d\pi-p\pi\) or \(d\pi-d\pi\) bonds is **true**. Thus, the final conclusion is: - **Assertion is false; Reason is true.** ### Summary of the Solution 1. The assertion is incorrect because heavier p-block elements do not form strong π bonds. 2. The reason is correct as it explains the type of bonds formed by heavier p-block elements.
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