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Complete the following reactions: (i) ...

Complete the following reactions:
(i) `C_(2)H_(5)I+H_(2) underset(C_(2)H_(5)OH)overset(Zn-Cu)toK`
(ii) `CH_(30COONa+H_(2)O overset("Electrolysis")toY`
(iii) `CH_(3)CH_(2)CH_(2)CH_(2)CH_(2)CH_(3) underset(773K)overset(Cr_(2)O_(3)//Al_(2)O_(3))toZ`

A

`X=C_(2)H_(6),Y=C_(2)H_(6),Z=C_(6)H_(6)`

B

`X=CH_(4),Y=CH_(30COOH,Z=CH_(3)CH_(3)`

C

`X=C_(2)H_(6),Y=CH_(4),Z=C_(4)H_(10)`

D

`X=C_(2)H_(6),Y=CH_(4),Z=C_(5)H_(10)`

Text Solution

AI Generated Solution

The correct Answer is:
Let's solve the reactions step by step. ### Reaction (i): **Given Reaction:** \[ C_2H_5I + H_2 \xrightarrow{Zn-Cu} X \] **Step 1:** Identify the reactants. - The reactant is iodoethane (\(C_2H_5I\)) and hydrogen gas (\(H_2\)). **Step 2:** Determine the type of reaction. - This is a reduction reaction where the iodine atom in iodoethane will be replaced by hydrogen. **Step 3:** Write the balanced equation. - The reaction will eliminate hydrogen iodide (HI) and form ethane (\(C_2H_6\)). **Final Product:** \[ X = C_2H_6 \] (Ethane) ### Reaction (ii): **Given Reaction:** \[ CH_3COONa + H_2O \xrightarrow{\text{Electrolysis}} Y \] **Step 1:** Identify the reactants. - The reactant is sodium acetate (\(CH_3COONa\)) and water (\(H_2O\)). **Step 2:** Determine the type of reaction. - This is an electrolysis reaction, which will lead to decarboxylation. **Step 3:** Write the balanced equation. - During electrolysis, sodium acetate will lose a carbon dioxide molecule (CO2) and form ethane (\(C_2H_6\)). **Final Product:** \[ Y = C_2H_6 \] (Ethane) ### Reaction (iii): **Given Reaction:** \[ CH_3CH_2CH_2CH_2CH_2CH_3 \xrightarrow{773K, Cr_2O_3//Al_2O_3} Z \] **Step 1:** Identify the reactants. - The reactant is n-hexane (\(C_6H_{14}\)). **Step 2:** Determine the type of reaction. - This is a dehydrogenation reaction that occurs at high temperatures, leading to cyclization and aromatization. **Step 3:** Write the balanced equation. - The n-hexane will undergo dehydrogenation and cyclization to form benzene (\(C_6H_6\)). **Final Product:** \[ Z = C_6H_6 \] (Benzene) ### Summary of Products: - \( X = C_2H_6 \) (Ethane) - \( Y = C_2H_6 \) (Ethane) - \( Z = C_6H_6 \) (Benzene) ---
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NCERT FINGERTIPS ENGLISH-HYDROCARBONS -Assertion And Reason
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