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How many geometrical isomers are possibl...

How many geometrical isomers are possible for the given compound?
`CH_(3)-CH=CH-CH=CH-C_(2)H_(5)`

A

Four

B

Three

C

Two

D

Five

Text Solution

AI Generated Solution

The correct Answer is:
To determine the number of geometrical isomers for the compound `CH3-CH=CH-CH=CH-C2H5`, we can follow these steps: ### Step 1: Identify the Double Bonds The given compound has two double bonds (C=C) between the carbon atoms. The presence of double bonds introduces the possibility of geometrical isomerism due to restricted rotation around these bonds. ### Step 2: Count the Restricted Rotations Each double bond can lead to two configurations: cis (same side) and trans (opposite sides). In this compound, we have two double bonds, which means we have two points of restricted rotation. ### Step 3: Use the Formula for Geometrical Isomers The number of geometrical isomers can be calculated using the formula: \[ \text{Number of geometrical isomers} = 2^n \] where \( n \) is the number of double bonds that can exhibit geometrical isomerism. In our case, \( n = 2 \) (since there are two double bonds). ### Step 4: Calculate the Number of Isomers Substituting \( n \) into the formula: \[ \text{Number of geometrical isomers} = 2^2 = 4 \] ### Step 5: Identify the Isomers We can identify the four geometrical isomers based on the configurations of the double bonds: 1. **Cis-Cis**: Both double bonds in the cis configuration. 2. **Cis-Trans**: The first double bond in cis and the second in trans. 3. **Trans-Cis**: The first double bond in trans and the second in cis. 4. **Trans-Trans**: Both double bonds in the trans configuration. ### Conclusion Thus, the total number of geometrical isomers for the compound `CH3-CH=CH-CH=CH-C2H5` is **4**. ---
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