Home
Class 11
CHEMISTRY
The alkene that exhibits geometrical iso...

The alkene that exhibits geometrical isomerism is

A

propene

B

2-methylpropene

C

2-butene

D

2-methyl-2-butene

Text Solution

AI Generated Solution

The correct Answer is:
To determine which alkene exhibits geometrical isomerism, we need to analyze the given options based on the criteria for geometrical isomerism (also known as cis-trans isomerism). This occurs when there is restricted rotation around a double bond and when two different groups are attached to each carbon of the double bond. ### Step-by-Step Solution: 1. **Understand the Criteria for Geometrical Isomerism**: - For an alkene to exhibit geometrical isomerism, it must have: - A double bond (C=C). - Different groups attached to each carbon of the double bond (i.e., A ≠ B and C ≠ D). 2. **Analyze Each Option**: - **Option A: Propene (CH3-CH=CH2)**: - The structure is CH3-CH=CH2. - The double bond is between the second and third carbon. - Both carbons involved in the double bond have identical hydrogen atoms (H), making it impossible to have different groups. - **Conclusion**: Propene does not exhibit geometrical isomerism. - **Option B: 2-Methylpropene (CH3-CH(CH3)-CH2)**: - The structure is CH3-CH(CH3)-CH2. - The double bond is between the second and third carbon. - Again, there are identical groups (H) on the double-bonded carbons. - **Conclusion**: 2-Methylpropene does not exhibit geometrical isomerism. - **Option C: 2-Butene (CH3-CH=CH-CH3)**: - The structure is CH3-CH=CH-CH3. - The double bond is between the second and third carbon. - The groups attached to the double-bonded carbons are different (one has CH3 and the other has H). - **Conclusion**: 2-Butene can exhibit geometrical isomerism (cis and trans forms). - **Option D: 2-Methyl-2-butene (CH3-C(CH3)=CH-CH3)**: - The structure is CH3-C(CH3)=CH-CH3. - The double bond is between the second and third carbon. - Both groups on the double-bonded carbon are identical (CH3), which means it cannot exhibit geometrical isomerism. - **Conclusion**: 2-Methyl-2-butene does not exhibit geometrical isomerism. 3. **Final Answer**: - The alkene that exhibits geometrical isomerism is **Option C: 2-Butene**.

To determine which alkene exhibits geometrical isomerism, we need to analyze the given options based on the criteria for geometrical isomerism (also known as cis-trans isomerism). This occurs when there is restricted rotation around a double bond and when two different groups are attached to each carbon of the double bond. ### Step-by-Step Solution: 1. **Understand the Criteria for Geometrical Isomerism**: - For an alkene to exhibit geometrical isomerism, it must have: - A double bond (C=C). - Different groups attached to each carbon of the double bond (i.e., A ≠ B and C ≠ D). ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • HYDROCARBONS

    NCERT FINGERTIPS ENGLISH|Exercise Higher Order Thinkin Skills|7 Videos
  • HYDROCARBONS

    NCERT FINGERTIPS ENGLISH|Exercise Assertion & Reason|15 Videos
  • EQUILIBRIUM

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos
  • HYDROGEN

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos

Similar Questions

Explore conceptually related problems

Out of the following the alkene that exhibits optical isomerism is

The compound (s) the exhibit(s) geometrical isomerism is (are ) :

Knowledge Check

  • Geometrical isomerism is caused

    A
    by restricted rotation around C=C bond
    B
    by the presence of one asymmetric carbon atom
    C
    due to the differennt groups attached to the same functional group
    D
    by swing of hydrogenn atom between two divalent atoms.
  • Which of the following types of compounds is unable to exhibit geometrical isomerism ?

    A
    abc = Cab
    B
    axC = Cay
    C
    aaC = Cab
    D
    none of these
  • Similar Questions

    Explore conceptually related problems

    Explain why compounds of the type aaC=Cab are unable to exhibit geometrical isomerism?

    Which of the following can exhibit geometrical isomerism?

    The geometrical isomerism is shown by:

    A: All square planar complexes can exhibit geometrical isomerism. R: In square planar complexes metal assumes sp^(3) hybridisation.

    Which of these will exhibit geometrical isomerism ?

    Which of these will exhibit geometrical isomerism ?