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An alkene 3-ethylpent-2-ene will give wh...

An alkene 3-ethylpent-2-ene will give which of the following products on ozonolysis?

A

`HCHO+CH_(3)CH_(2)CH_(2)CHO`

B

C

D

`CH_(3)CH_(2)CHO+CH_(3)CH_(2)CH_(2)CH_(2)CHO`

Text Solution

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The correct Answer is:
To determine the products of ozonolysis for the alkene 3-ethylpent-2-ene, we will follow these steps: ### Step 1: Identify the Structure of the Alkene The alkene given is 3-ethylpent-2-ene. This means: - The longest carbon chain has 5 carbon atoms (pent). - There is a double bond between the second and third carbon atoms (pent-2-ene). - An ethyl group (C2H5) is attached to the third carbon. The structure can be drawn as follows: ``` CH2CH3 | CH3-CH-CH=CH-CH3 ``` ### Step 2: Understand Ozonolysis Ozonolysis is a reaction where an alkene reacts with ozone (O3) to form an ozonide intermediate, which is then typically reduced by zinc (Zn) to yield carbonyl compounds (aldehydes or ketones). ### Step 3: Form the Ozonide Intermediate When 3-ethylpent-2-ene undergoes ozonolysis, it forms an unstable 5-membered ring (ozonide) as an intermediate: ``` O / \ CH3-CH-CH-CH-CH3 \ / O ``` ### Step 4: Break the Ozonide The unstable ozonide will break down to form carbonyl compounds. The double bond between the second and third carbon will cleave, resulting in: - An aldehyde from the carbon chain that was part of the double bond. - A ketone from the other part of the carbon chain. ### Step 5: Identify the Products From the breakdown of the ozonide: 1. The aldehyde formed will be from the terminal carbon (C1) and the carbon (C2) that was part of the double bond: - **Aldehyde**: CH3C(=O)H (which is propanal) 2. The ketone formed will be from the carbon chain that includes the ethyl group (C3 and C4): - **Ketone**: CH3CH2C(=O)CH2CH3 (which is 2-pentanone) ### Final Products Thus, the products of ozonolysis of 3-ethylpent-2-ene are: - Propanal (an aldehyde) - 2-pentanone (a ketone) ### Conclusion The correct answer to the question is that 3-ethylpent-2-ene will yield propanal and 2-pentanone upon ozonolysis. ---

To determine the products of ozonolysis for the alkene 3-ethylpent-2-ene, we will follow these steps: ### Step 1: Identify the Structure of the Alkene The alkene given is 3-ethylpent-2-ene. This means: - The longest carbon chain has 5 carbon atoms (pent). - There is a double bond between the second and third carbon atoms (pent-2-ene). - An ethyl group (C2H5) is attached to the third carbon. ...
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NCERT FINGERTIPS ENGLISH-HYDROCARBONS -Assertion And Reason
  1. An alkene 3-ethylpent-2-ene will give which of the following products ...

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  2. Assertion: 2,2-Dimethylbutane does not have any tertiary carbon atom. ...

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  3. Assertion: The reaction, C(2)H(5)Br +2Na+C(2)H(5)Br to C(4)H(10)+2NaBr...

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  4. Assertion: Wurtz reaction is not preferred for the preparation of alka...

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  5. Assertion: Sodium salt of butanoic acid on heating with soda lime give...

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  6. Assertion: Boiling point of pentane is higher than 2,2-dimethylpropane...

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  7. Assertion: Iodination of alkanes is carried out in the presence of oxi...

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  8. Assertion: Staggered conformation of ethane is most stable while eclip...

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  9. Assertion: cis-form of alkene is found to be more polar than the trans...

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  10. Assertion: Alkenes are easily attacked by electrophilic reagents. Re...

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  11. Assertion: Addition of HBr to propene yields 2-bromopropane but in pre...

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  12. Assertion: Decolourisation of KMnO(4) solution is used as a test for u...

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  13. Assertion: Ethyne reacts with sodium metal and sodamide to form sodium...

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  14. Assertion: Cyclopentadienyl anion is aromatic in nature. Reason: Cyc...

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  15. Assertion: The second substituent may enter the mono-substituted benze...

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  16. Assertion: In case of aryl halides, halogens are moderately deactivati...

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